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Which of the following is a Lewis base?


A) BCl3
B) Cu2+
C) Cl-
D) Mn2+
E) NH4+

F) D) and E)
G) All of the above

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Phosphoric acid, H3PO4, is a triprotic acid, for which Ka1 = 7.2 × 10-3, Ka2 = 6.3 × 10-8 and Ka3 = 4.2 × 10-13. What is the value of Kb for the hydrogen phosphate anion, HPO4?


A) 6.3 × 10-8
B) 4.2 × 10-13
C) 1.4 × 10-12
D) 1.6 × 10-7
E) 2.4 × 10-2

F) A) and B)
G) B) and C)

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Picric acid has been used in the leather industry and in etching copper. However, its laboratory use has been restricted because it dehydrates on standing and can become shock sensitive. It has an acid dissociation constant of 0.42. What is the [H3O+] for a 0.20 M solution of picric acid?


A) 0.022 M
B) 0.052 M
C) 0.15 M
D) 0.29 M
E) None of these choices are correct.

F) A) and B)
G) A) and E)

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The substance Ca(OH) 2 is considered


A) a weak Arrhenius acid.
B) a weak Arrhenius base.
C) a strong Arrhenius acid.
D) a strong Arrhenius base.
E) a neutral compound.

F) C) and E)
G) B) and D)

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All Brønsted-Lowry bases contain the hydroxide ion, OH-.

A) True
B) False

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The substance (CH3CH2) 2NH is considered


A) a weak acid.
B) a weak base.
C) a strong acid.
D) a strong base.
E) a neutral compound.

F) B) and C)
G) A) and E)

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Arrhenius bases raise the hydroxide ion concentration when dissolved in water.

A) True
B) False

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Which of the following liquids contains the strongest acid?


A) 0.1 M HA, pH = 6.85
B) 0.1 M HD, pH = 7.22
C) 0.1 M HE, pH = 8.34
D) 0.1 M HJ, pH = 11.88
E) pure water

F) C) and E)
G) D) and E)

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Which of the following is not a characteristic property of bases?


A) taste bitter
B) turn litmus from pink to blue
C) neutralize acids
D) react with carbonates to produce carbon dioxide gas
E) feel slippery

F) A) and E)
G) A) and B)

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What is the pH of a 0.050 M triethylamine, (C2H5) 3N, solution? Kb for triethylamine is 5.3 × 10-4.


A) 11.69
B) 8.68
C) 5.32
D) 2.31
E) < 2.0

F) All of the above
G) A) and B)

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A solution is prepared by adding 0.10 mol of potassium acetate, KCH3COO, to 1.00 L of water. Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) The concentrations of potassium ions and acetate ions will be identical.
E) The concentration of acetate ions will be greater than the concentration of potassium ions.

F) A) and D)
G) C) and D)

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Formic acid, which is a component of insect venom, has a Ka = 1.8 × 10-4. What is the [H3O+] in a solution that is initially 0.10 M formic acid, HCOOH?


A) 4.2 × 10-3 M
B) 8.4 × 10-3 M
C) 1.8 × 10-4 M
D) 1.8 × 10-5 M
E) 1.8 × 10-6 M

F) C) and D)
G) None of the above

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What is the pH of a 0.0100 M sodium benzoate solution? Kb (C7H5O2) = 1.5 × 10-10


A) 0.38
B) 5.91
C) 8.09
D) 9.82
E) 13.62

F) A) and E)
G) None of the above

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All Brønsted-Lowry bases have at least one lone pair of electrons.

A) True
B) False

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The substance NH3 is considered


A) a weak acid.
B) a weak base.
C) a strong acid.
D) a strong base.
E) a neutral compound.

F) A) and D)
G) D) and E)

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What is the pH of a 0.050 M LiOH solution?


A) < 1.0
B) 1.30
C) 3.00
D) 11.00
E) 12.70

F) A) and D)
G) B) and E)

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Hydroxylamine, HONH2, readily forms salts such as hydroxylamine hydrochloride which are used as antioxidants in soaps. Hydroxylamine has Kb of 9.1 × 10-9. What is the pH of a 0.025 M HONH2 solution?


A) 2.90
B) 4.82
C) 9.18
D) 9.91
E) 11.10

F) B) and D)
G) B) and C)

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Arsenic acid, H3AsO4, is used industrially to manufacture insecticides. Arsenic acid is a polyprotic acid with K1 = 2.5 × 10-4, K2 = 5.6 × 10-8, and K3 = 3 × 10-13. What is the concentration of the HAsO42- in a solution whose initial arsenic acid concentration was 0.35 M?


A) 9.4 × 10-3 M
B) 2.5 × 10-4 M
C) 8.8 × 10-5 M
D) 5.6 × 10-8 M
E) None of these choices are correct.

F) B) and E)
G) A) and D)

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What is the [OH-] for a solution at 25°C that has [H3O+] = 8.23 × 10-2 M?


A) > 10-5 M
B) 1.22 × 10-6 M
C) 8.23 × 10-12 M
D) 1.22 × 10-13 M
E) 8.23 × 10-16 M

F) C) and E)
G) All of the above

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The chloride ion, Cl-, is a typical Lewis acid.

A) True
B) False

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