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Which of the following statements about voltaic and electrolytic cells is correct?


A) The electrons in the external wire flow from cathode to anode in both types of cell.
B) Oxidation occurs at the cathode only in a voltaic cell.
C) The free energy change, Δ\Delta G, is negative for an electrolytic cell.
D) The cathode is labeled as positive (+) in a voltaic cell but negative (-) in an electrolytic cell.
E) Reduction occurs at the anode in an electrolytic cell.

F) A) and D)
G) A) and C)

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A voltaic cell consists of a Ag/Ag+ electrode (E °\degree = 0.80 V) and a Fe2+/Fe3+ electrode (E °\degree = 0.77 V) with the following initial molar concentrations: [Fe2+] = 0.30 M; [Fe3+] = 0.10 M; [Ag+] = 0.30 M. What is the equilibrium concentration of Fe3+? (Assume the anode and cathode solutions are of equal volume, and a temperature of 25 °\degree C.)


A) 0.030 M
B) 0.043 M
C) 0.085 M
D) 0.11 M
E) 0.17 M

F) C) and E)
G) A) and C)

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Electrolytic cells utilize electrical energy to drive non-spontaneous redox reactions.

A) True
B) False

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The line notation, Pt | H2(g) | H+(aq) || Cu2+(aq) | Cu(s) , indicates that


A) copper metal is a product of the cell reaction.
B) hydrogen gas (H2) is a product of the cell reaction.
C) Cu is the anode.
D) Pt is the cathode.
E) Cu2+ is the reducing agent.

F) A) and E)
G) A) and D)

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Calculate the potential of a voltaic cell (E °\degree cell) if it is required to do 5.43 * 10¯3 kJ of work when a charge of 2.50 C is transferred.


A) 2.17* 103 V
B) 2.17 * 10¯3 V
C) 2.17 V
D) 13.6 V
E) 1.36 * 10¯2 V

F) B) and D)
G) B) and C)

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If the electrodes of a voltaic cell are connected with an external wire, electrons will flow in this wire from the cathode to the anode.

A) True
B) False

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A secondary cell (battery) can operate either as a galvanic or an electrolytic cell.

A) True
B) False

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A buried iron pipe can be protected against corrosion by connecting it to a rod of copper.

A) True
B) False

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Chromium metal is electroplated from acidic aqueous solutions containing the dichromate ion, Cr2O72¯. What is the minimum time needed to plate out 10.0 g of chromium metal from such a solution, if the current is 50.0 A?


A) 6.2 minutes
B) 12.4 minutes
C) 18.6 minutes
D) 24.7 minute
E) 37.1 minutes

F) A) and C)
G) A) and B)

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What is the E °\degree cell for the cell represented by the combination of the following half-reactions?  What is the E \degree <sub>cell</sub> for the cell represented by the combination of the following half-reactions?   A)  -0.398 V B)  -2.380 V C)  0.398 V D)  2.380 V E)  None of these choices is correct.


A) -0.398 V
B) -2.380 V
C) 0.398 V
D) 2.380 V
E) None of these choices is correct.

F) B) and D)
G) A) and B)

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Explain what is meant by a fuel cell. Provide a balanced equation to represent the reaction in any fuel cell of your choice.

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A fuel cell is a voltaic cell in which t...

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A voltaic cell consists of a Cd/Cd2+ electrode (E °\degree = -0.40 V) and a Fe/Fe2+ electrode (E °\degree = -0.44 V) . If Ecell = 0 and the temperature is 25 °\degree C, what is the ratio [Fe2+]/[Cd2+]?


A) 2 *101
B) 1 *101
C) 1
D) 1 *10¯1
E) 5 *10¯2

F) B) and D)
G) C) and E)

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In the shorthand notation for cells, a single vertical line represents a salt bridge.

A) True
B) False

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Write down equations representing the anode half-reaction, the cathode half-reaction and the overall cell reaction for the lead-acid battery.

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Which, if any, of the following metals would be capable of acting as a sacrificial anode when used with iron pipe? E °\degree Fe = -0.44 V; all E °\degree values refer to the M2+/M half-cell reactions.


A) copper, Cu, E °\degree = 0.15 V
B) cobalt, Co, E °\degree = -0.28 V
C) chromium, Cr, E °\degree = -0.74 V
D) tin, Sn, E °\degree = -0.14 V
E) None of these metals would be capable of acting as a sacrificial anode with iron.

F) A) and E)
G) B) and C)

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Calculate E °\degree cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous.  Calculate E \degree <sub>cell</sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous.   Overall reaction:   A)  E \degree <sub>cell</sub> = -1.23 V, spontaneous B)  E \degree <sub>cell</sub> = -1.23 V, nonspontaneous C)  E \degree <sub>cell</sub> = 1.23 V, spontaneous D)  E \degree <sub>cell</sub> = 1.23 V, nonspontaneous E)  E \degree <sub>cell</sub> = -0.05 V, nonspontaneous Overall reaction:  Calculate E \degree <sub>cell</sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous.   Overall reaction:   A)  E \degree <sub>cell</sub> = -1.23 V, spontaneous B)  E \degree <sub>cell</sub> = -1.23 V, nonspontaneous C)  E \degree <sub>cell</sub> = 1.23 V, spontaneous D)  E \degree <sub>cell</sub> = 1.23 V, nonspontaneous E)  E \degree <sub>cell</sub> = -0.05 V, nonspontaneous


A) E °\degree cell = -1.23 V, spontaneous
B) E °\degree cell = -1.23 V, nonspontaneous
C) E °\degree cell = 1.23 V, spontaneous
D) E °\degree cell = 1.23 V, nonspontaneous
E) E °\degree cell = -0.05 V, nonspontaneous

F) B) and E)
G) A) and B)

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A concentration cell consists of two Zn/Zn2+ electrodes. The electrolyte in compartment A is 0.10 M Zn(NO3) 2 and in compartment B is 0.60 M Zn(NO3) 2. What is the voltage of the cell at 25 °\degree C?


A) 0.010 V
B) 0.020 V
C) 0.023 V
D) 0.046 V
E) None of these choices is correct.

F) A) and E)
G) B) and C)

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A much-studied cell in electrochemistry has the following cell notation: A much-studied cell in electrochemistry has the following cell notation:   Bearing in mind that HCl(aq) consists of H<sup>+</sup>(aq) and Cl¯(aq), and that this solution is in contact with both electrodes (there is no salt bridge), write down balanced equations for A) the anode half-reaction. B) the cathode half-reaction. C) the cell reaction. Bearing in mind that HCl(aq) consists of H+(aq) and Cl¯(aq), and that this solution is in contact with both electrodes (there is no salt bridge), write down balanced equations for A) the anode half-reaction. B) the cathode half-reaction. C) the cell reaction.

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a. 11ec9252_5a81_4f64_b435_411...

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Which of the following elements can be isolated by electrolysis of the aqueous salt shown?


A) phosphorus from K3PO4(aq)
B) sodium from NaBr(aq)
C) aluminum from AlCl3(aq)
D) fluorine from KF(aq)
E) iodine from NaI(aq)

F) A) and D)
G) B) and C)

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Electrons are produced at the cathode of a voltaic cell.

A) True
B) False

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