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Balance the following equation for the combustion of benzene: C6H6(l) + O2(g) → H2O(g) + CO2(g)


A) C 6H 6( l) + 9O 2( g) → 3H 2O( g) + 6CO 2( g)
B) C 6H 6( l) + 9O 2( g) → 6H 2O( g) + 6CO 2( g)
C) 2C 6H 6(l) + 15O 2(g) → 6H 2O(g) + 12CO 2( g)
D) C 6H 6( l) + 15O 2( g) → 3H 2O( g) + 6CO 2( g)
E) 2C 6H 6( l) + 9O 2( g) → 6H 2O( g) + 12CO 2( g)

F) B) and C)
G) B) and D)

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Phosphorus pentachloride, PCl5, a white solid that has a pungent, unpleasant odor, is used as a catalyst for certain organic reactions. Calculate the number of moles in 38.7 g of PCl5.


A) 5.38 mol
B) 3.55 mol
C) 0.583 mol
D) 0.282 mol
E) 0.186 mol

F) B) and E)
G) C) and D)

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Potassium chlorate (used in fireworks, flares, and safety matches) forms oxygen and potassium chloride when heated. KClO3(s) → KCl(s) + O2(g) [unbalanced] How many grams of oxygen are formed when 26.4 g of potassium chlorate is heated?


A) 223 g
B) 99.1 g
C) 10.3 g
D) 6.86 g
E) 4.60 g

F) A) and E)
G) C) and E)

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Household sugar, sucrose, has the molecular formula C12H22O11. What is the percent of carbon in sucrose, by mass?


A) 26.7%
B) 33.3%
C) 41.4%
D) 42.1%
E) 52.8%

F) None of the above
G) B) and E)

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Constitutional (structural) isomers have the same empirical formula but different molecular formulas.

A) True
B) False

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Balance the following equation: C8H18O3(l) + O2(g) → H2O(g) + CO2(g)


A) C 8H 18O 3( l) + 8O 2( g) → 9H 2O( g) + 8CO 2( g)
B) C 8H 18O 3( l) + 11O 2( g) → 9H 2O( g) + 8CO 2( g)
C) 2C 8H 18O 3( l) + 22O 2( g) → 9H 2O( g) + 16CO 2( g)
D) C 8H 18O 3( l) + 13O 2( g) → 18H 2O( g) + 8CO 2( g)
E) 2C 8H 18O 3( l) + 17O 2( g) → 18H 2O( g) + 16CO 2( g)

F) B) and E)
G) A) and E)

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Hydroxylamine nitrate contains 29.17 mass % N, 4.20 mass % H, and 66.63 mass % O. Determine its empirical formula.


A) HNO
B) H 2NO 2
C) HN 6O 16
D) HN 16O 7
E) H 2NO 3

F) B) and D)
G) A) and B)

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Constitutional (structural) isomers have the same molecular formula but different structural formulas.

A) True
B) False

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In a blast furnace, elemental iron is produced from a mixture of coke (C) , iron ore (Fe3O4) , and other reactants. An important reaction sequence is 2C(s) + O2(g) → 2CO(g) Fe3O4(s) + 4CO(g) → 3Fe(l) + 4CO2(g) How many moles of iron can be formed in this sequence when 1.00 mol of carbon, as coke, is consumed?


A) 6.00 mol Fe
B) 3.00 mol Fe
C) 1.33 mol Fe
D) 1.25 mol Fe
E) 0.750 mol Fe

F) B) and E)
G) A) and B)

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Potassium chloride is used as a substitute for sodium chloride for individuals with high blood pressure. Identify the limiting reactant and determine the mass of the excess reactant remaining when 7.00 g of chlorine gas reacts with 5.00 g of potassium to form potassium chloride.


A) Potassium is the limiting reactant; 2.47 g of chlorine remain.
B) Potassium is the limiting reactant; 7.23 g of chlorine remain.
C) Chlorine is the limiting reactant; 4.64 g of potassium remain.
D) Chlorine is the limiting reactant; 2.70 g of potassium remain.
E) No limiting reagent: the reactants are present in the correct stoichiometric ratio.

F) B) and C)
G) A) and E)

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The formula CH3O0.5 is an example of an empirical formula.

A) True
B) False

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One mole of methane (CH4) contains a total of 3 × 1024 atoms.

A) True
B) False

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Gadolinium oxide, a colorless powder which absorbs carbon dioxide from the air, contains 86.76 mass % Gd. Determine its empirical formula.


A) Gd 2O 3
B) Gd 3O 2
C) Gd 3O 4
D) Gd 4O 3
E) GdO

F) C) and E)
G) A) and B)

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In a correctly balanced equation, the number of reactant molecules must equal the number of product molecules. A)118.15 g/mol B)99.15 g/mol C)78.07 g/mol D)59.08 g/mol E)50.01 g/mol

A) True
B) False

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Lead(II) sulfide was once used in glazing earthenware. It will also react with hydrogen peroxide to form lead(II) sulfate and water. How many grams of hydrogen peroxide are needed to react completely with 265 g of lead(II) sulfide?


A) 151 g
B) 123 g
C) 50.3 g
D) 37.7 g
E) 9.41 g

F) None of the above
G) A) and B)

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A compound of bromine and fluorine is used to make UF6, which is an important chemical in processing and reprocessing of nuclear fuel. The compound contains 58.37 mass percent bromine. Determine its empirical formula.


A) BrF
B) BrF 2
C) Br 2F 3
D) Br 3F
E) BrF 3

F) C) and D)
G) A) and D)

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Lead (II) nitrate is a poisonous substance which has been used in the manufacture of special explosives and as a sensitizer in photography. Calculate the mass of lead in 139 g of Pb(NO3) 2.


A) 107 g
B) 90.8 g
C) 87.0 g
D) 83.4 g
E) 62.6 g

F) C) and D)
G) None of the above

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In combustion analysis, the carbon and hydrogen contents of a substance are determined from the CO2 and H2O, respectively, which are collected in the absorbers.

A) True
B) False

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Methanol (CH4O) is converted to bromomethane (CH3Br) as follows: CH4O + HBr → CH3Br + H2O If 12.23 g of bromomethane are produced when 5.00 g of methanol is reacted with excess HBr, what is the percentage yield?


A) 40.9%
B) 82.6%
C) 100%
D) 121%
E) 245%

F) A) and E)
G) None of the above

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A compound containing chromium and silicon contains 73.52 mass percent chromium. Determine its empirical formula.


A) CrSi 3
B) Cr 2Si 3
C) Cr 3Si
D) Cr 3Si 2
E) Cr 2S

F) C) and D)
G) None of the above

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