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A voltaic cell consists of a Cd/Cd2+ electrode (E° = -0.40 V) and a Fe/Fe2+ electrode (E° = -0.44 V) . If Ecell = 0 and the temperature is 25°C, what is the ratio [Fe2+]/[Cd2+]?


A) 2.3 × 101
B) 1.0 × 101
C) 1.0
D) 1.0 × 10-1
E) 5.0 × 10-2

F) None of the above
G) A) and B)

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Consider the following balanced redox reaction. Mn2+(aq) + S2O82-(aq) + 2H2O(l) → MnO2(s) + 4H+(aq) + 2SO42-(aq) Which of the following statements is true?


A) Mn2+(aq) is the oxidizing agent and is reduced.
B) Mn2+(aq) is the oxidizing agent and is oxidized.
C) Mn2+(aq) is the reducing agent and is oxidized.
D) Mn2+(aq) is the reducing agent and is reduced.
E) Manganese does not change its oxidation number in this reaction.

F) A) and D)
G) All of the above

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What is E°cell for a galvanic cell represented by the combination of the following half-reactions? What is E°<sub>cell</sub> for a galvanic cell represented by the combination of the following half-reactions?   A)  -0.398 V B)  -2.380 V C)  0.398 V D)  2.380 V E)  6.539 V


A) -0.398 V
B) -2.380 V
C) 0.398 V
D) 2.380 V
E) 6.539 V

F) C) and D)
G) All of the above

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The voltaic cell composed of Co(s) , Co2+(aq) , Cu(s) , and Cu2+(aq) has E°cell = 0.62 V. If E° of the cathode half-cell is 0.34 V, what is E° of the anode half-cell? Cu2+(aq) + Co(s) → Cu(s) + Co2+(aq)


A) -0.28 V
B) -0.96 V
C) 0.28 V
D) 0.96 V
E) 0.21 V

F) A) and D)
G) All of the above

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What is ΔG° at 200°C for the following reaction? (F = 96,500 C • mol -1) 2Na(l) + FeCl2(s) What is ΔG° at 200°C for the following reaction? (F = 96,500 C • mol<sup> -1</sup>)  2Na(l)  + FeCl<sub>2</sub>(s)    2NaCl(s)  + Fe(s)  E°<sub>cell</sub> = 2.35 V A)  454 kJ/mol B)  -454 kJ/mol C)  907 kJ/mol D)  -907 kJ/mol E)  227 kJ/mol 2NaCl(s) + Fe(s) E°cell = 2.35 V


A) 454 kJ/mol
B) -454 kJ/mol
C) 907 kJ/mol
D) -907 kJ/mol
E) 227 kJ/mol

F) A) and D)
G) A) and C)

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________ is the process that uses electrical energy to drive a nonspontaneous chemical reaction.

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If ΔG° of the following reaction is -110 kJ/mol, what is E°cell? (F = 96,500 C • mol -1) A3+(aq) + 3B(s) → A(s) + 3B+(aq)


A) +0.38 V
B) -0.09 V
C) -0.38 V
D) +0.00038 V
E) +0.09 V

F) A) and E)
G) B) and D)

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What is ΔG° for the reaction of iron(II) ions with one mole of permanganate ions? (F = 96,500 C • mol -1) What is ΔG° for the reaction of iron(II)  ions with one mole of permanganate ions? (F = 96,500 C • mol<sup> -1</sup>)    A)  -71.4 kJ B)  -286 kJ C)  -357 kJ D)  -428 kJ E)  None of these choices is correct.


A) -71.4 kJ
B) -286 kJ
C) -357 kJ
D) -428 kJ
E) None of these choices is correct.

F) A) and E)
G) B) and D)

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Which is the correct cell diagram for the following electrochemical cell? Which is the correct cell diagram for the following electrochemical cell?     A)  Sn(s)  | Sn<sup>2+</sup>(aq, 1.0 M)  || Fe<sup>2+</sup>(aq, 1.0 M)  | Fe(s)  B)  Sn(s)  | Fe<sup>2+</sup>(aq, 1.0 M)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Fe(s)  C)  Fe(s)  | Sn<sup>2+</sup>(aq, 1.0 M)  || Fe<sup>2+</sup>(aq, 1.0 M)  | Sn(s)  D)  Fe(s)  | Fe<sup>2+</sup>(aq, 1.0 M)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Sn(s)  E)  Sn(s)  | Fe(s)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Fe<sup>2+</sup>(aq, 1.0 M) Which is the correct cell diagram for the following electrochemical cell?     A)  Sn(s)  | Sn<sup>2+</sup>(aq, 1.0 M)  || Fe<sup>2+</sup>(aq, 1.0 M)  | Fe(s)  B)  Sn(s)  | Fe<sup>2+</sup>(aq, 1.0 M)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Fe(s)  C)  Fe(s)  | Sn<sup>2+</sup>(aq, 1.0 M)  || Fe<sup>2+</sup>(aq, 1.0 M)  | Sn(s)  D)  Fe(s)  | Fe<sup>2+</sup>(aq, 1.0 M)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Sn(s)  E)  Sn(s)  | Fe(s)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Fe<sup>2+</sup>(aq, 1.0 M)


A) Sn(s) | Sn2+(aq, 1.0 M) || Fe2+(aq, 1.0 M) | Fe(s)
B) Sn(s) | Fe2+(aq, 1.0 M) || Sn2+(aq, 1.0 M) | Fe(s)
C) Fe(s) | Sn2+(aq, 1.0 M) || Fe2+(aq, 1.0 M) | Sn(s)
D) Fe(s) | Fe2+(aq, 1.0 M) || Sn2+(aq, 1.0 M) | Sn(s)
E) Sn(s) | Fe(s) || Sn2+(aq, 1.0 M) | Fe2+(aq, 1.0 M)

F) A) and B)
G) A) and C)

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Which is the half-reaction at the cathode in a lead storage battery?


A) Pb(s) + PbO2(s) + 4H+(aq) + 2SO42-(aq) → 2PbSO4(s) + 2H2O(l)
B) PbO2(s) + 4H+(aq) + 2SO42-(aq) + 2e- → PbSO4(s) + 2H2O(l)
C) Pb(s) + SO42-(aq) → PbSO4(s) + 2e-
D) Pb(s) → Pb(s) + 2e-
E) H2(g) → 2H+(aq) + 2e-

F) A) and B)
G) A) and C)

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Based on the data presented below, which is the strongest reducing agent? Based on the data presented below, which is the strongest reducing agent?   A)  Pb(s)  B)  Ca(s)  C)  Pt(s)  D)  Br<sup>-</sup>(aq)  E)  Pt<sup>2+</sup>(aq)


A) Pb(s)
B) Ca(s)
C) Pt(s)
D) Br-(aq)
E) Pt2+(aq)

F) All of the above
G) A) and B)

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What is the name given to the apparatus where oxidation occurs in a cell where electricity flows?


A) Cathode
B) Electrode
C) Galvanic cell
D) Anode
E) Voltaic cell

F) A) and E)
G) None of the above

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Which metals may be oxidized by H+ under standard-state conditions? Which metals may be oxidized by H<sup>+</sup> under standard-state conditions?   A)  Ag, Cu, Sn, and Zn B)  Ag and Cu C)  Sn and Cu D)  Zn and Cu E)  Zn and Sn


A) Ag, Cu, Sn, and Zn
B) Ag and Cu
C) Sn and Cu
D) Zn and Cu
E) Zn and Sn

F) B) and E)
G) C) and E)

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What mass of oxygen gas is produced in the electrolysis of water, for every gram of hydrogen gas formed? Reaction: 2H2O(l) → 2H2(g) + O2(g)


A) 32 g O2
B) 16 g O2
C) 64 g O2
D) 20 g O2
E) 8 g O2

F) A) and E)
G) A) and C)

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How many minutes would be required to electroplate 25.0 g of chromium by passing a constant current of 4.80 A through a solution containing CrCl3?


A) 483 min
B) 161 min
C) 322 min
D) 2.01 × 104 min
E) 1.11 × 104 min

F) C) and D)
G) B) and D)

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What quantity of charge is required to cause reduction of 0.20 mole of Cr3+ to Cr?


A) 0.60 C
B) 3.0 C
C) 1.9 × 104 C
D) 5.8 × 104 C
E) 9.7 × 104 C

F) A) and E)
G) All of the above

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What is E°cell for the following reaction? 2Au(s) + 3Ca2+(aq) → 2Au3+(aq) + 3Ca(s) What is E°<sub>cell</sub> for the following reaction? 2Au(s)  + 3Ca<sup>2+</sup>(aq)  → 2Au<sup>3+</sup>(aq)  + 3Ca(s)    A)  -4.37 V B)  -1.37 V C)  -11.6 V D)  1.37 V E)  4.37 V


A) -4.37 V
B) -1.37 V
C) -11.6 V
D) 1.37 V
E) 4.37 V

F) All of the above
G) B) and E)

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Electrons flow to the cathode in a voltaic cell.

A) True
B) False

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Which statement is correct?


A) The cathode is the electrode where the oxidation takes place.
B) The cathode is the electrode where the reduction takes place.
C) Both oxidation and reduction make take place at the cathode, depending on the cell.
D) The cathode is always positive.
E) The anode is always negative.

F) A) and D)
G) A) and E)

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Which equation is correct?


A) Ecell = RT lnK
B) ΔG = -nFEcell
C) Ecell = -RT lnK
D) K = E°cell/nRT
E) E°cell = -nFlnK

F) B) and D)
G) A) and B)

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