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Which results in a buffered solution?


A) A solution containing a strong acid and its conjugate base
B) A solution containing a strong base and its conjugate acid
C) A solution containing a catalyst
D) A solution containing two organic liquids
E) A solution containing a weak acid and its conjugate base

F) C) and D)
G) All of the above

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A 20.0-mL sample of 0.25 M HNO3 is titrated with 0.15 M NaOH. What is the pH of the solution after 30.0 mL of NaOH have been added to the acid?


A) 2.00
B) 1.60
C) 1.05
D) 1.00
E) 0.00

F) B) and E)
G) A) and E)

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Which is more soluble in an acidic solution than in pure water?


A) CH3CH2OH, ethanol
B) Li2O
C) C6H12O6, glucose
D) CCl4
E) ICl3

F) None of the above
G) C) and D)

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Calculate the NaOH concentration necessary to precipitate Ca(OH) 2 from a solution in which [Ca2+] = 1.0. Ksp of Ca(OH) 2 = 8 x 10-6.


A) 6.7 x 10-8 M
B) 2.8 x 10-3 M
C) 1.5 x 10-7 M
D) 0.10 M

E) None of the above
F) All of the above

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The molar solubility of manganese(II) carbonate is 4.2 × 10-6 M. What is Ksp for this compound?


A) 4.2 × 10-6
B) 8.4 × 10-6
C) 3.0 × 10-16
D) 1.8 × 10-11
E) 2.0 × 10-3

F) D) and E)
G) C) and E)

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Which is more soluble in an acidic solution than in pure water?


A) CuI
B) PbCl2
C) Ca3(PO4) 2
D) NaNO3
E) NaBr

F) C) and E)
G) A) and E)

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Calculate the pH of a buffer solution that contains 0.25 M benzoic acid (C6H5CO2H) and 0.15 M sodium benzoate (C6H5COONa) . (Ka = 6.5 × 10-5 for benzoic acid)


A) 3.97
B) 4.83
C) 4.19
D) 3.40
E) 4.41

F) A) and C)
G) All of the above

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What happens to the solution if sodium acetate is added to a solution of acetic acid? CH3COOH(aq) What happens to the solution if sodium acetate is added to a solution of acetic acid? CH<sub>3</sub>COOH(aq)    H<sup>+</sup>(aq)  + CH<sub>3</sub>COO<sup>-</sup>(aq)  A)  The equilibrium shifts to the right. B)  There is an increase in percent ionization of acetic acid. C)  Less of hydrogen ion is consumed. D)  There is an increased concentration of acetate ions. E)  Less of the acetate ion is consumed. H+(aq) + CH3COO-(aq)


A) The equilibrium shifts to the right.
B) There is an increase in percent ionization of acetic acid.
C) Less of hydrogen ion is consumed.
D) There is an increased concentration of acetate ions.
E) Less of the acetate ion is consumed.

F) B) and C)
G) A) and D)

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A 50.0-mL sample of 0.50 M HCl is titrated with 0.50 M NaOH. What is the pH of the solution after 28.0 mL of NaOH have been added to the acid?


A) 0.85
B) 2.96
C) 2.85
D) 1.49
E) 3.81

F) B) and D)
G) A) and B)

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When sodium acetate is added to a solution of acetic acid, what happens to the pH of the solution? Explain why this effect occurs? CH3COOH(aq) When sodium acetate is added to a solution of acetic acid, what happens to the pH of the solution? Explain why this effect occurs? CH<sub>3</sub>COOH(aq)   H<sup>+</sup>(aq)CH<sub>3</sub>COO<sup>-</sup>(aq) H+(aq)CH3COO-(aq)

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The pH increases because the equilibrium...

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A 35.0-mL sample of 0.20 M LiOH is titrated with 0.25 M HCl. What is the pH of the solution after 23.0 mL of HCl have been added to the base?


A) 1.26
B) 1.67
C) 12.33
D) 12.74
E) 13.03

F) B) and C)
G) C) and D)

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If the pH of a buffer solution is greater than the pKa value of the buffer acid, the buffer will have more capacity to neutralize added base than added acid.

A) True
B) False

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The ________ is the point in a titration where neutralization is complete.

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What is the [H3O+] in a buffer that consists of 0.30 M HCOOH and 0.20 M HCOONa? [Ka(HCOOH) = 1.7 × 10-4]


A) 1.1 × 10-4 M
B) 2.6 × 10-4 M
C) 4.3 × 10-4 M
D) 6.7 × 10-5 M
E) 1.7 × 10-4 M

F) B) and D)
G) C) and D)

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A 25.0-mL sample of 0.10 M C2H5NH2 (ethylamine) is titrated with 0.15 M HCl. What is the pH of the solution after 9.00 mL of acid have been added to the amine? [Kb(C2H5NH2) = 6.5 × 10-4]


A) 11.08
B) 10.74
C) 10.81
D) 10.55
E) 10.49

F) A) and E)
G) B) and E)

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Calculate the solubility of silver oxalate, Ag2C2O4, in pure water. [Ksp(Ag2C2O4) = 1.0 × 10-11]


A) 1.4 × 10-4 M
B) 8.2 × 10-5 M
C) 5.4 × 10-5 M
D) 3.2 × 10-6 M
E) 2.5 × 10-12 M

F) C) and D)
G) A) and B)

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A 25.0-mL sample of 1.00 M NH3 is titrated with 0.15 M HCl. What is the pH of the solution after 15.00 mL of acid have been added to the ammonia solution? [Kb(NH3) = 1.8 × 10-5]


A) 10.26
B) 9.30
C) 9.21
D) 8.30
E) 8.21

F) B) and D)
G) A) and B)

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A mixture made of 100 mL of 0.5 M CH3COOH and 100 mL of 0.5 M CH3COONa is classified as a buffer solution.

A) True
B) False

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What is the ion product expression for magnesium fluoride, MgF2?


A) What is the ion product expression for magnesium fluoride, MgF<sub>2</sub>? A)    B)    C)    D)    E)
B) What is the ion product expression for magnesium fluoride, MgF<sub>2</sub>? A)    B)    C)    D)    E)
C) What is the ion product expression for magnesium fluoride, MgF<sub>2</sub>? A)    B)    C)    D)    E)
D) What is the ion product expression for magnesium fluoride, MgF<sub>2</sub>? A)    B)    C)    D)    E)
E) What is the ion product expression for magnesium fluoride, MgF<sub>2</sub>? A)    B)    C)    D)    E)

F) B) and C)
G) A) and D)

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What is the pH of a solution prepared by mixing 500.mL of 0.10 M NaOCl and 500. mL of 0.20 M HOCl? [Ka(HOCl) = 3.2 × 10-8]


A) 4.10
B) 7.00
C) 7.19
D) 7.49
E) 7.80

F) B) and E)
G) B) and D)

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