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What is the pressure in atmospheres exerted by a column of mercury that is 100. m high? (density of mercury = 13.5951 g/cm3, gravitational constant = 9.80665 m/s2, 1 atm = 101,325 Pa = 760 torr = 760 mmHg)


A) 1.4 × 1010 atm
B) 0.013 atm
C) 0.73 atm
D) 1.37 atm
E) 132 atm

F) B) and C)
G) A) and E)

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A compound composed of carbon, hydrogen, and chlorine effuses through a pinhole 0.411 times as fast as neon. What is the molecular formula of the compound?


A) CHCl3
B) CH2Cl2
C) C2H2Cl2
D) C2H3Cl
E) CCl4

F) B) and D)
G) C) and D)

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A gas evolved during the fermentation of sugar was collected at 22.5°C and 702 mmHg. After purification its volume was found to be 25.0 L. How many moles of gas were collected? (R = 0.08206 L • atm/K • mol, 1 atm = 760 mmHg)


A) 0.952 mol
B) 1.05 mol
C) 12.5 mol
D) 22.4 mol
E) 724 mol

F) B) and C)
G) A) and E)

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What is the volume of NH3 produced in the following reaction when 3.0 L of N2 reacts with 4.0 L of H2 ? N2(g) + 3H2(g) → 2NH3(g)


A) 1.5 L
B) 2.7 L
C) 6.0 L
D) 7.5 L
E) 12 L

F) B) and C)
G) B) and E)

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A 0.271-g sample of an unknown vapor occupies 294 mL at 140°C and 847 mmHg. The empirical formula of the compound is CH2. What is the molecular formula of the compound? (R = 0.08206 L • atm/K • mol)


A) CH2
B) C2H4
C) C3H6
D) C4H8
E) C6H12

F) A) and B)
G) A) and C)

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The air pressure in a volleyball is 75 psi. What is this pressure in torr? (1 atm = 14.7 psi = 101,325 Pa = 760 torr) ?


A) 520 torr
B) 562 torr
C) 3900 torr
D) 7600 torr
E) 75,000 torr

F) A) and B)
G) A) and C)

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The Kelvin temperature scale is useful when comparing


A) various gas samples at different densities.
B) volume of a gas sample with temperature at constant pressure.
C) pressure of gas samples at different volumes and constant temperature.
D) various liquids at constant pressure.

E) A) and B)
F) None of the above

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What is the standard pressure used for STP conditions?

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1 atm or 7...

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What is the initial pressure of a gas having an initial temperature of 905 K, an initial volume of 14.3 L, a final pressure of 0.83 atm, a final temperature of 154 K and a final volume of 2.7 L?


A) 26 atm
B) 0.27 atm
C) 0.75 atm
D) 1.3 atm
E) 0. 92 atm

F) A) and B)
G) A) and E)

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1.000 atm of oxygen gas, placed in a container having a pinhole opening in its side, leaks from the container 2.14 times faster than does 1.000 atm of an unknown gas placed in this same apparatus. Which of the following species could be the unknown gas?


A) Cl2
B) SF6
C) Kr
D) UF6
E) Xe

F) A) and C)
G) A) and E)

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"The pressure of an ideal gas is inversely proportional to its volume at constant temperature and number of moles" is a statement of ________ law.


A) Charles's
B) Boyle's
C) Amontons's
D) Avogadro's
E) Gay-Lussac's

F) All of the above
G) None of the above

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A sample of nitrogen gas has a volume of 32.4 L at 20°C. The gas is heated to 220ºC at constant pressure. What is the final volume of the nitrogen gas?


A) 2.94 L
B) 19.3 L
C) 32.4 L
D) 54.5 L
E) 356 L

F) All of the above
G) A) and B)

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A sample of a gas occupies 1.40 L at 25°C and 760 mmHg. What volume will it occupy at the same temperature and 380 mmHg?


A) 2.8 L
B) 2.10 L
C) 1.40 L
D) 1.05 L
E) 0.700 L

F) B) and E)
G) B) and C)

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In the van der Waals equation, the constant b is a constant that is part of a correction factor for ________.


A) the volume of the gas
B) the temperature of the gas
C) the pressure of the gas
D) the ideal gas constant

E) C) and D)
F) B) and D)

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A(n) ________ is a device used to measure the pressure of gases other than the atmosphere.

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Give five examples of compounds that exist as gases at room temperature and atmospheric pressure.

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(Answers will vary.)...

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Gases are sold in large cylinders for laboratory use. What pressure is exerted by 2.500 kg of oxygen gas (O2) stored at 22°C in a 40.0-L cylinder? (R = 0.08206 L • atm/K • mol)


A) 3.55 atm
B) 1.51 ×103 atm
C) 47.3 atm
D) 7.56 × 104 atm
E) 10.2 atm

F) All of the above
G) A) and B)

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The rate of diffusion of a gas is inversely proportional to its molar mass.

A) True
B) False

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The mole fraction of oxygen molecules in dry air is 0.2095. What volume of dry air at 1.00 atm and 25°C is required for burning completely 1.00 L of octane (C8H18, density = 0.7025 g/mL) , yielding carbon dioxide and water? (R = 0.08206 L • atm/K • mol)


A) 394 L
B) 1880 L
C) 8220 L
D) 8970 L
E) 17,900 L

F) A) and E)
G) B) and D)

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Consider the following reaction. H2(g) + I2(s) → 2 HI(g) If the cylinder with a movable piston below contains 1 mol H2(g) and 1 mol I2(s) , which represents the cylinder after the reaction is complete? Consider the following reaction. H<sub>2</sub>(g)  + I<sub>2</sub>(s)  → 2 HI(g)  If the cylinder with a movable piston below contains 1 mol H<sub>2</sub>(g)  and 1 mol I<sub>2</sub>(s) , which represents the cylinder after the reaction is complete?   A)    B)    C)    D)    E)  None of these choices.


A) Consider the following reaction. H<sub>2</sub>(g)  + I<sub>2</sub>(s)  → 2 HI(g)  If the cylinder with a movable piston below contains 1 mol H<sub>2</sub>(g)  and 1 mol I<sub>2</sub>(s) , which represents the cylinder after the reaction is complete?   A)    B)    C)    D)    E)  None of these choices.
B) Consider the following reaction. H<sub>2</sub>(g)  + I<sub>2</sub>(s)  → 2 HI(g)  If the cylinder with a movable piston below contains 1 mol H<sub>2</sub>(g)  and 1 mol I<sub>2</sub>(s) , which represents the cylinder after the reaction is complete?   A)    B)    C)    D)    E)  None of these choices.
C) Consider the following reaction. H<sub>2</sub>(g)  + I<sub>2</sub>(s)  → 2 HI(g)  If the cylinder with a movable piston below contains 1 mol H<sub>2</sub>(g)  and 1 mol I<sub>2</sub>(s) , which represents the cylinder after the reaction is complete?   A)    B)    C)    D)    E)  None of these choices.
D) Consider the following reaction. H<sub>2</sub>(g)  + I<sub>2</sub>(s)  → 2 HI(g)  If the cylinder with a movable piston below contains 1 mol H<sub>2</sub>(g)  and 1 mol I<sub>2</sub>(s) , which represents the cylinder after the reaction is complete?   A)    B)    C)    D)    E)  None of these choices.
E) None of these choices.

F) A) and B)
G) B) and E)

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