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What is the molecular geometry of N2O as predicted by the VSEPR model? What is the molecular geometry of N<sub>2</sub>O as predicted by the VSEPR model?   A)  trigonal pyramidal B)  trigonal planar C)  tetrahedral D)  bent E)  linear


A) trigonal pyramidal
B) trigonal planar
C) tetrahedral
D) bent
E) linear

F) C) and D)
G) A) and B)

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What is the molecular geometry of XeO2F2 as predicted by the VSEPR model? What is the molecular geometry of XeO<sub>2</sub>F<sub>2</sub> as predicted by the VSEPR model?   A)  square planar B)  tetrahedral C)  square pyramidal D)  seesaw E)  octahedral


A) square planar
B) tetrahedral
C) square pyramidal
D) seesaw
E) octahedral

F) A) and E)
G) C) and D)

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The angles between sp2 hybrid orbitals are 109.5°.

A) True
B) False

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What is the molecular geometry of NO2- as predicted by the VSEPR model?


A) linear
B) trigonal planar
C) bent
D) tetrahedral
E) trigonal pyramidal

F) All of the above
G) B) and C)

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The nitrosonium ion, NO+, forms a number of interesting complexes with nickel, cobalt, and iron. According to molecular orbital theory, which statement about NO+ is correct?


A) NO+ has a bond order of 2 and is paramagnetic.
B) NO+ has a bond order of 2 and is diamagnetic.
C) NO+ has a bond order of 3 and is paramagnetic.
D) NO+ has a bond order of 3 and is diamagnetic.
E) NO+ has a bond order of 2.5 and is neither paramagnetic nor diamagnetic.

F) All of the above
G) None of the above

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Which one of the following molecules is nonpolar?


A) CO2
B) PF3
C) KCl
D) IBr3
E) CHCl3

F) A) and E)
G) A) and D)

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A

According to the VSEPR model, a molecule with the general formula AB5 with one lone pair on the central atom will have a ________ molecular geometry.


A) tetrahedral
B) trigonal bipyramidal
C) square pyramidal
D) octahedral
E) seesaw

F) B) and D)
G) B) and E)

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The Lewis structure of formaldehyde, CH2O, is shown. Use VSEPR model to predict the molecular geometry and the H-C-H bond angle. Outline your reasoning. The Lewis structure of formaldehyde, CH<sub>2</sub>O, is shown. Use VSEPR model to predict the molecular geometry and the H-C-H bond angle. Outline your reasoning.

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There are three electron groups around t...

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How do you describe the molecular geometry of a molecule that has more than one central atom?


A) You describe the molecular geometry around the most electronegative atom.
B) You describe the molecular geometry around each central atom separately.
C) You describe the molecular geometry around the most electropositive atom.
D) You describe the molecular geometry around the atom with the largest atomic radius.
E) You describe the molecular geometry around the atom with the largest bond angle.

F) C) and D)
G) B) and E)

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Which is the most reasonable prediction for the H-O-H bond angle in H2O?


A) 90°
B) 109.5°
C) 120°
D) 107°
E) 105°

F) D) and E)
G) C) and D)

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According to the VSEPR model, is the molecule PF5 polar or nonpolar?

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Which is true for carbon monoxide?


A) CO has a short CO bond.
B) CO has a zero dipole moment.
C) The bond energy in CO is low.
D) The atoms in CO cannot obey the octet rule.
E) All of these are true about CO.

F) A) and D)
G) A) and C)

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According to molecular orbital (MO) theory, the twelve valence electrons in the O2 molecule are distributed as follows:


A) 12 in bonding MOs, 0 in antibonding MOs.
B) 10 in bonding MOs, 2 in antibonding MOs.
C) 9 in bonding MOs, 3 in antibonding MOs.
D) 8 in bonding MOs, 4 in antibonding MOs.
E) 7 in bonding MOs, 5 in antibonding MOs.

F) A) and B)
G) B) and D)

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What is the total number of electron domains around the central atom for a molecule having a T-shaped molecular geometry, such as BrF3?


A) 5
B) 2
C) 3
D) 4
E) 6

F) All of the above
G) A) and D)

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A

In the valence bond treatment, a π bond is formed when two p orbitals overlap side to side.

A) True
B) False

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Predict the molecular geometry and polarity of the SO2 molecule.


A) linear, polar
B) linear, nonpolar
C) bent, polar
D) bent, nonpolar
E) trigonal planar, polar

F) B) and D)
G) B) and E)

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How many bonds are there in one molecule of 1,5-hexadiyne (shown below) ? How many bonds are there in one molecule of 1,5-hexadiyne (shown below) ?   A)  2 B)  4 C)  6 D)  11 E)  15


A) 2
B) 4
C) 6
D) 11
E) 15

F) All of the above
G) A) and B)

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B

To make an sp3 hybrid orbital, one s atomic orbital is mixed with three p atomic orbitals.

A) True
B) False

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Thiocarbonyl disulfide (CSF2) , based on the coordinate axes provided below, in which direction does the net molecular dipole moment point for the molecule? Thiocarbonyl disulfide (CSF<sub>2</sub>) , based on the coordinate axes provided below, in which direction does the net molecular dipole moment point for the molecule?   A)  It points in the +x direction. B)  It points in the -x direction. C)  It points in the +y direction. D)  It points in the -y direction. E)  The molecule does not have a net molecular dipole moment.


A) It points in the +x direction.
B) It points in the -x direction.
C) It points in the +y direction.
D) It points in the -y direction.
E) The molecule does not have a net molecular dipole moment.

F) C) and D)
G) A) and D)

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Carbon uses ________ hybrid orbitals in ClCN.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and B)
G) All of the above

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