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Which of the following is D-glucose? Which of the following is D-glucose?   A)  I B)  II C)  III D)  IV


A) I
B) II
C) III
D) IV

E) A) and B)
F) A) and C)

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What are the products of the following reaction? What are the products of the following reaction?   A)  D B)  A C)  C D)  B


A) D
B) A
C) C
D) B

E) A) and B)
F) A) and C)

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Which of the following is D-fructose? Which of the following is D-fructose?   A)  I B)  IV C)  II D)  III


A) I
B) IV
C) II
D) III

E) A) and C)
F) B) and C)

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A

After a series of Kiliani-Fischer syntheses on D-glyceraldehyde, an unknown sugar was isolated from the reaction mixture. The following experimental data was obtained. What is the structure of this unknown sugar? Data: - Molecular formula: C6H12O6 - Reacts with phenylhydrazine to give an osazone, mp 178°C. - Reacts with HNO3 to give an optically active aldaric acid. - Wohl degradation followed by HNO3 oxidation gives an optically inactive aldaric acid. - Two Wohl degradations followed by HNO3 oxidation give a meso-tartaric acid. After a series of Kiliani-Fischer syntheses on D-glyceraldehyde, an unknown sugar was isolated from the reaction mixture. The following experimental data was obtained. What is the structure of this unknown sugar? Data: - Molecular formula: C<sub>6</sub>H<sub>12</sub>O<sub>6</sub> - Reacts with phenylhydrazine to give an osazone, mp 178°C. - Reacts with HNO<sub>3</sub> to give an optically active aldaric acid. - Wohl degradation followed by HNO<sub>3</sub> oxidation gives an optically inactive aldaric acid. - Two Wohl degradations followed by HNO<sub>3</sub> oxidation give a meso-tartaric acid.    A)  D B)  C C)  A D)  B


A) D
B) C
C) A
D) B

E) A) and D)
F) A) and C)

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C

Amylose is a polysaccharide with ________ linkages.


A) a-1,4'-glycosidic
B) a-1,6'-glycosidic
C) b-1,4'-glycosidic
D) b-1,6'-glycosidic

E) None of the above
F) A) and B)

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Cellulose is a polysaccharide with ________ linkages.


A) a-1,4'-glycosidic
B) b-1,6'-glycosidic
C) b-1,4'-glycosidic
D) a-1,6'-glycosidic

E) A) and B)
F) C) and D)

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What is the composition of sucrose?


A) Repeating unit of glucose units joined in a b-1,4'-glycosidic linkage
B) Two glucose units with a a-1,4'-glycoside bond
C) One galactose and one glucose unit with a b-1,4'-glycoside bond
D) One glucose and one fructose unit with a a-glycosidic bond to the 2' carbon of a fructofuranose ring

E) None of the above
F) A) and D)

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What type of linkage is present in chitin?


A) beta-1,2'-glycosidic linkage
B) alpha-1,2'-glycosidic linkage
C) alpha-1,4'-glycosidic linkage
D) beta-1,4'-glycosidic linkage

E) A) and B)
F) A) and C)

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D

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