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The structural form of the element Ge closely resembles the structure of


A) C (diamond) .
B) N (diatomic) .
C) As (tetrahedral) .
D) S (S8 ring) .
E) Kr (monatomic) .

F) C) and E)
G) A) and B)

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The molar enthalpy of vaporization of boron tribromide is 30.5 kJ/mol, and its normal boiling point is 91°C. What is the vapor pressure of BBr3 at 20°C?


A) 11.5 torr
B) 311 torr
C) 5.31 torr
D) 143 torr
E) 66.1 torr

F) A) and B)
G) A) and C)

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Which of the following properties indicates the presence of weak intermolecular forces in a liquid?


A) a high heat of vaporization
B) a high critical temperature
C) a high vapor pressure
D) a high boiling point
E) None of the above.

F) D) and E)
G) A) and B)

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Which of the following substances would have the highest critical temperature?


A) CH3Cl
B) C2H6
C) F2
D) H2
E) CO2

F) B) and C)
G) B) and E)

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Octane is a liquid component of gasoline. Given the following vapor pressures of octane at various temperatures, estimate the boiling point of octane in Leadville, Colorado, where the atmospheric pressure is 496 mmHg. 400 mmHg @ 104°C, 500 mmHg @ 111°C, 600 mmHg @ 117°C, 700 mmHg @ 122°C, 760 mmHg @ 125°C


A) 125°C
B) 120°C
C) 115°C
D) 110°C
E) 105°C

F) A) and B)
G) All of the above

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What phase exists at the point labeled a? What phase exists at the point labeled a?

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The triple point of iodine is at 0.12 atm and 115°C. Thus, liquid I2


A) is more dense than I2 (s) .
B) cannot exist above 115°C.
C) is liquid at room temperature.
D) cannot have a vapor pressure less than 91 torr.

E) B) and C)
F) All of the above

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Platinum has a face-centered cubic crystal structure and a density of 21.5 g/cm3. What is the radius of the platinum atom?


A) 69 pm
B) 98 pm
C) 139 pm
D) 196 pm
E) 277 pm

F) All of the above
G) A) and B)

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Use the graph of vapor pressure to determine the normal boiling point of O2. Use the graph of vapor pressure to determine the normal boiling point of O<sub>2</sub>.   A) 92 K B) 90 K C) 88 K D) 84 K E) O<sub>2</sub> doesn't boil because it is always a gas.


A) 92 K
B) 90 K
C) 88 K
D) 84 K
E) O2 doesn't boil because it is always a gas.

F) A) and D)
G) D) and E)

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Potassium crystallizes in a body-centered cubic lattice. How many atoms are there per unit cell?


A) 1
B) 2
C) 4
D) 6
E) 8

F) A) and B)
G) B) and E)

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Which of the following liquids would have the highest viscosity at 25°C?


A) CH3OCH3
B) CH2Cl2
C) C2H5OH
D) CH3Br
E) HOCH2CH2OH

F) None of the above
G) A) and B)

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The molecular property related to the ease with which the electron density in a neutral atom or molecule can be distorted is called


A) a dipole moment.
B) polarizability.
C) a dispersion force.
D) surface tension.
E) a van der Waals force.

F) A) and B)
G) B) and E)

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Which one of the following substances should exhibit hydrogen bonding in the liquid state?


A) PH3
B) H2
C) H2S
D) CH4
E) NH3

F) A) and B)
G) B) and E)

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Use the graph of vapor pressure to determine the normal boiling point of CHCl3. Use the graph of vapor pressure to determine the normal boiling point of CHCl<sub>3</sub>.   A) 19°C B) 52°C C) 60°C D) 64°C E) 70°C


A) 19°C
B) 52°C
C) 60°C
D) 64°C
E) 70°C

F) A) and D)
G) D) and E)

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Given the following liquids and their boiling points, which has the highest vapor pressure at its normal boiling point?


A) ethanol, bp = 78°C
B) methanol, bp = 65°C
C) water, bp = 100°C
D) benzene, bp = 80°C
E) The vapor pressure of each of the liquids at its normal boiling point would be the same.

F) B) and C)
G) C) and D)

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The molar heats of sublimation and fusion of iodine are 62.3 kJ/mol and15.3 kJ/mol, respectively. Calculate the molar heat of vaporization of liquid iodine.


A) 77.6 kJ/mol
B) 47.0 kJ/mol
C) -47.0 kJ/mol
D) -77.6 kJ/mol
E) 4.07 kJ/mol

F) All of the above
G) B) and E)

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Copper crystallizes in a face-centered cubic unit cell. The density of copper is 8.94 g/cm3. Calculate the length of the edge of the unit cell in pm.

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Given that the heat of vaporization of diethyl ether is 26.0 kJ/mol and the vapor pressure of diethyl ether is 440 torr at 20.°C, calculate the normal boiling point of diethyl ether.

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36°C (the ...

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Of the given pair of compounds, which would have the higher boiling point? CH3Cl or CH4

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Find the temperature at which water boils on a day in the mountains when the barometric pressure is 593 mmHg. (Given: the heat of vaporization of water is 40.79 kJ/mol)


A) 93.1°C
B) 117°C
C) 41.5°C
D) 97.0°C
E) 68.1°C

F) B) and C)
G) C) and E)

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