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A system absorbs 21.6 kJ of heat while performing 6.9 kJ of work on the surroundings.If the initial internal energy,E,is 61.2 kJ,what is the final value of E?


A) 32.7 kJ
B) 46.5 kJ
C) 75.9 kJ
D) 82.8 kJ
E) 89.7 kJ

F) B) and D)
G) B) and E)

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The only way in which a system can do work on the surroundings is by expansion against the external pressure.

A) True
B) False

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Galena is the ore from which elemental lead is extracted.In the first step of the extraction process,galena is heated in air to form lead(II) oxide. Galena is the ore from which elemental lead is extracted.In the first step of the extraction process,galena is heated in air to form lead(II) oxide.   What mass of galena is converted to lead oxide if 975 kJ of heat are liberated? A) 203 g B) 282 g C) 406 g D) 478 g E) 564 g What mass of galena is converted to lead oxide if 975 kJ of heat are liberated?


A) 203 g
B) 282 g
C) 406 g
D) 478 g
E) 564 g

F) A) and B)
G) B) and C)

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Different chemical bonds have different potential energies.

A) True
B) False

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a.State Hess's Law. b.Use the Δ\Delta H° data given below to calculate Δ\Delta H° for the reaction: C2H4(g)+ H2(g) \to C2H6(g) Data:  a.State Hess's Law. b.Use the  \Delta H° data given below to calculate  \Delta H° for the reaction: C<sub>2</sub>H<sub>4</sub>(g)+ H<sub>2</sub>(g)  \to  C<sub>2</sub>H<sub>6</sub>(g) Data:

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a.The enthalpy change for an o...

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Which one of the following is not a correct formation reaction? (products are correct)


A) H2(g) + O(g) \to H2O(l)
B)
 Which one of the following is not a correct formation reaction? (products are correct)  A) H<sub>2</sub>(g) + O(g)   \to  H<sub>2</sub>O(l)  B)    H<sub>2</sub>(g) +   Cl<sub>2</sub>(g)   \to  HCl(g)  C) 6C(graphite) + 3H<sub>2</sub>(g)   \to  C<sub>6</sub>H<sub>6</sub>(l)  D) C(graphite)   \to  C(diamond)  E) 6C(graphite) + 6H<sub>2</sub>(g) + 3O<sub>2</sub>(g)   \to C<sub>6</sub>H<sub>12</sub>O<sub>6</sub>(s)
H2(g) +
 Which one of the following is not a correct formation reaction? (products are correct)  A) H<sub>2</sub>(g) + O(g)   \to  H<sub>2</sub>O(l)  B)    H<sub>2</sub>(g) +   Cl<sub>2</sub>(g)   \to  HCl(g)  C) 6C(graphite) + 3H<sub>2</sub>(g)   \to  C<sub>6</sub>H<sub>6</sub>(l)  D) C(graphite)   \to  C(diamond)  E) 6C(graphite) + 6H<sub>2</sub>(g) + 3O<sub>2</sub>(g)   \to C<sub>6</sub>H<sub>12</sub>O<sub>6</sub>(s)
Cl2(g) \to HCl(g)
C) 6C(graphite) + 3H2(g) \to C6H6(l)
D) C(graphite) \to C(diamond)
E) 6C(graphite) + 6H2(g) + 3O2(g) \to C6H12O6(s)

F) A) and B)
G) D) and E)

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Calculate the Δ\Deltarxn for the following reaction. Δ\Deltaf [SiO2(s) ] = -910.9 kJ/mol;F Δ\Deltaf [SiCl4(g) ] = -657.0 kJ/mol; Δ\Deltaf [HCl(g) ] = -92.3 kJ/mol; Δ\Deltaf [H2O (g) ] = -241.8 kJ/mol SiO2(s) + 4HCl(g) \to SiCl4(g) + 2H2O(g)


A) -139.5 kJ
B) -137.4 kJ
C) -104.4 kJ
D) 104.4 kJ
E) 139.5 kJ

F) A) and E)
G) B) and E)

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A system which undergoes an adiabatic change and does work on the surroundings has


A) w < 0, Δ\Delta E = 0
B) w > 0, Δ\Delta E > 0
C) w > 0, Δ\Delta E < 0
D) w < 0, Δ\Delta E > 0
E) w < 0, Δ\Delta E < 0

F) A) and B)
G) A) and C)

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a.Write a balanced equation for the combustion of benzene,C6H6(l)in oxygen. b.The standard heat of combustion of benzene is -3271 kJ/mol.Calculate its standard heat of formation, Δ\Deltaf ,given the data: Δ\Deltaf [CO2(g)] = -394 kJ; Δ\Deltaf [H2O(l)] = -286 kJ

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a.C6H6(l...

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If,as a pioneer,you wished to warm your room by taking an object heated on top of a pot-bellied stove to it,which of the following 15-pound objects,each heated to 100°C,would be the best choice? The specific heat capacity (in J/(g·K) ) for each substance is given in parentheses.Iron (0.450) ,copper (0.387) ,granite (0.79) ,gold (0.129) ,water (4.18) .


A) iron
B) copper
C) granite
D) gold
E) water

F) All of the above
G) C) and D)

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Use the following data to calculate the standard heat (enthalpy) of formation, Δ\Deltaf ,of manganese(IV) oxide,MnO2 (s) .  Use the following data to calculate the standard heat (enthalpy) of formation, \Delta H°<sub>f</sub> ,of manganese(IV) oxide,MnO<sub>2</sub> (s) .   A) -504 kJ B) -372 kJ C) -24 kJ D) 24 kJ E) 504 kJ


A) -504 kJ
B) -372 kJ
C) -24 kJ
D) 24 kJ
E) 504 kJ

F) B) and C)
G) All of the above

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Given the following data:  Given the following data:     calculate  \Delta H° for the reaction NO(g)+ O(g) \to NO<sub>2</sub>(g) calculate Δ\Delta H° for the reaction NO(g)+ O(g) \to NO2(g)

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Use Hess's Law to calculate the enthalpy change for the reaction WO3(s) + 3H2(g) \to W(s) + 3H2O(g) From the following data:  Use Hess's Law to calculate the enthalpy change for the reaction WO<sub>3</sub>(s) + 3H<sub>2</sub>(g)   \to  W(s) + 3H<sub>2</sub>O(g)  From the following data:   A) 125.9 kJ B) 252.9 kJ C) 364.9 kJ D) 1207.6 kJ E) None of these choices is correct.


A) 125.9 kJ
B) 252.9 kJ
C) 364.9 kJ
D) 1207.6 kJ
E) None of these choices is correct.

F) C) and E)
G) D) and E)

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A 275-g sample of nickel at l00.0°C is placed in 100.0 mL of water at 22.0°C.What is the final temperature of the water? Assume that no heat is lost to or gained from the surroundings.Specific heat capacity of nickel = 0.444 J/(g·K)


A) 39.6°C
B) 40.8°C
C) 61.0°C
D) 79.2°C
E) 82.4°C

F) C) and E)
G) All of the above

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Δ\Delta H does not depend on the path of a reaction,but Δ\Delta E does.

A) True
B) False

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Ethanol,C2H5OH,is being promoted as a clean fuel and is used as an additive in many gasoline mixtures.Calculate the Δ\Deltarxn for the combustion of ethanol. Δ\Deltaf [C2H5OH(l) ] = -277.7 kJ/mol; Δ\Deltaf [CO2(g) ] = -393.5 kJ/mol; Δ\Deltaf [H2O(g) ] = -241.8 kJ/mol


A) -1234.7 kJ
B) -751.1 kJ
C) -357.6 kJ
D) 357.6 kJ
E) 1234.7 kJ

F) A) and D)
G) B) and D)

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Your favorite candy bar,Gummy Beakers,contains 1.2 ×\times 106 J of energy while your favorite soft drink,Bolt,contains 6.7 ×\times 105 J.If you eat two packs of Gummy Beakers a day and drink 3 cans of Bolt,what percent of your 2000 Calorie daily food intake is left for broccoli,beans,beef,etc.?


A) 53%
B) 47%
C) 27%
D) 11%
E) 0%

F) A) and B)
G) A) and E)

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In an endothermic reaction,in going from the reactants to the products at the same temperature,the value of q is negative.

A) True
B) False

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Ethylene glycol,used as a coolant in automotive engines,has a specific heat capacity of 2.42 J/(g·K) .Calculate q when 3.65 kg of ethylene glycol is cooled from 132°C to 85°C.


A) -1900 kJ
B) -420 kJ
C) -99 kJ
D) -0.42 kJ
E) -4.2 ×\times 10-6 kJ

F) A) and B)
G) A) and C)

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The highly exothermic thermite reaction,in which aluminum reduces iron(III) oxide to elemental iron,has been used by railroad repair crews to weld rails together. The highly exothermic thermite reaction,in which aluminum reduces iron(III) oxide to elemental iron,has been used by railroad repair crews to weld rails together.   What mass of iron is formed when 725 kJ of heat are released? A) 47 g B) 65 g C) 95 g D) 112 g E) 130 g What mass of iron is formed when 725 kJ of heat are released?


A) 47 g
B) 65 g
C) 95 g
D) 112 g
E) 130 g

F) C) and D)
G) A) and E)

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