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What is the pH of a solution that consists of 0.50 M H2C6H6O6 (ascorbic acid) and 0.75 M NaHC6H6O6 (sodium ascorbate) ? Ka = 6.8 ×\times 10-5


A) 3.76
B) 3.99
C) 4.34
D) 4.57
E) 5.66

F) All of the above
G) A) and C)

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Calculate the solubility of silver phosphate,Ag3PO4,in pure water.Ksp = 2.6 ×\times 10-18


A) 4.0 ×\times 10-5 M
B) 1.8 ×\times 10-5 M
C) 4.0 ×\times 10-6 M
D) 1.5 ×\times 10-6 M
E) < 1.0 ×\times 10-6 M

F) A) and E)
G) C) and D)

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A buffer is prepared by adding 150 mL of 1.0 M NaOH to 250 mL of 1.0 M NaH2PO4.How many moles of HCl must be added to this buffer solution to change the pH by 0.18 units?


A) 0.025 mol HCl
B) 0.063 mol HCl
C) 0.082 mol HCl
D) 0.50 mol HCl
E) 1.0 mol HCl

F) None of the above
G) B) and D)

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The solubility of magnesium phosphate is 2.27 ×\times 10-3 g/1.0 L of solution.What is the Ksp for Mg3(PO4) 2?


A) 6.5 ×\times 10-12
B) 6.0 ×\times 10-14
C) 5.2 ×\times 10-24
D) 4.8 ×\times 10-26
E) 1.0 ×\times 10-26

F) None of the above
G) A) and B)

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A solution is prepared by adding 500 mL of 0.3 M NaClO to 500 mL of 0.4 M HClO.What is the pH of this solution?


A) The pH will be greater than the pKa of hypochlorous acid.
B) The pH will be less than the pKa of hypochlorous acid.
C) The pH will be equal to the pKa of hypochlorous acid.
D) The pH will equal the pKb of sodium hypochlorite.
E) The pH will be none of these.

F) A) and B)
G) B) and E)

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The solubility of aluminum hydroxide in water ______________ when dilute nitric acid is added to it.


A) increases
B) decreases
C) does not change
D) first increases,then decreases
E) first decreases,then increases

F) All of the above
G) A) and E)

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Write the ion product expression for calcium phosphate,Ca3(PO4) 2.


A)
Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(PO<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E) None of these is the correct ion product expression.
B)
Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(PO<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E) None of these is the correct ion product expression.
C)
Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(PO<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E) None of these is the correct ion product expression.
D)
Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(PO<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E) None of these is the correct ion product expression.
E) None of these is the correct ion product expression.

F) A) and D)
G) B) and E)

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Which one of the following pairs of 0.100 mol L-1 solutions,when mixed,will produce a buffer solution?


A) 50.mL of aqueous CH3COOH and 25.mL of aqueous HCl
B) 50.mL of aqueous CH3COOH and 100.mL of aqueous NaOH
C) 50.mL of aqueous NaOH and 25.mL of aqueous HCl
D) 50.mL of aqueous CH3COONa and 25.mL of aqueous NaOH
E) 50.mL of aqueous CH3COOH and 25.mL of aqueous CH3COONa

F) B) and E)
G) C) and D)

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Hydrochloric acid (0.100 mol L-1,25.00 mL aliquot)is being titrated with sodium hydroxide of the same molarity.Calculate the solution pH after addition of 24.80 mL of the sodium hydroxide.Make any reasonable approximations.

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An acetate buffer has a pH of 4.40.Which of the following changes will cause the pH to decrease?


A) dissolving a small amount of solid sodium acetate
B) adding a small amount of dilute hydrochloric acid
C) adding a small amount of dilute sodium hydroxide
D) dissolving a small amount of solid sodium chloride
E) diluting the buffer solution with water

F) All of the above
G) A) and B)

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What volume of 0.500 M H2SO4 is needed to react completely with 20.0 mL of 0.400 M LiOH?


A) 4.00 mL
B) 8.00 mL
C) 12.5 mL
D) 16.0 mL
E) 32.0 mL

F) A) and C)
G) B) and E)

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Increasing the concentrations of the components of a buffer solution will increase the buffer capacity.

A) True
B) False

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What is the maximum amount of sodium sulfate that can be added to 1.00 L of 0.0020 M Ca(NO3) 2 before precipitation of calcium sulfate begins? Ksp = 2.4 ×\times 10-5 for calcium sulfate


A) 1.2 ×\times 10-2 mol
B) 4.9 ×\times 10-3 mol
C) 3.5 ×\times 10-3 mol
D) 1.2 ×\times 10-5 mol
E) 4.8 ×\times 10-8 mol

F) A) and B)
G) B) and E)

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The solubility of silver chromate is 0.0287 g/1.0 L of solution.What is the Ksp for Ag2CrO4?


A) 9.5 ×\times 10-5
B) 2.4 ×\times 10-5
C) 2.6 ×\times 10-12
D) 6.5 ×\times 10-13
E) < 1.0 ×\times 10-13

F) C) and E)
G) C) and D)

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A 25.0-mL sample of 0.10 M C2H3NH2 (ethylamine) is titrated with 0.15 M HCl.What is the pH of the solution after 9.00 mL of acid have been added to the amine? Kb = 6.5 ×\times 10-4


A) 11.08
B) 10.88
C) 10.74
D) 10.55
E) 10.49

F) A) and C)
G) C) and E)

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Which one of the following aqueous solutions,when mixed with an equal volume of 0.10 mol L-1 aqueous NH3,will produce a buffer solution?


A) 0.10 mol L-1 HCl
B) 0.20 mol L-1 HCl
C) 0.10 mol L-1 CH3COOH
D) 0.050 mol L-1 NaOH
E) 0.20 mol L-1 NH4Cl

F) A) and B)
G) B) and E)

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What is the pH of 375 mL of solution containing 0.150 mol of propenoic acid (HA)and 0.250 mol of sodium propenoate (NaA)? (Ka for propenoic acid is 5.52 ×\times 10-5. )

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Lead(II)iodide,PbI2,is an ionic compound with a solubility product constant Ksp of 7.9 ×\times 10-9.Calculate the solubility of this compound in a.pure water. b.0.50 mol L-1 KI solution.

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What is the [H3O+] in a solution that consists of 1.5 M NH3 and 2.5 NH4Cl? Kb = 1.8 ×\times 10-5


A) 1.1 ×\times 10-5 M
B) 3.0 ×\times 10-6 M
C) 3.3 ×\times 10-9 M
D) 9.3 ×\times 10-10 M
E) None of these choices is correct.

F) A) and E)
G) B) and D)

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What is the [H3O+] in a buffer that consists of 0.30 M HCOOH and 0.20 M HCOONa? Ka = 1.7 ×\times 10-4


A) 1.1 ×\times 10-4 M
B) 2.6 ×\times 10-4 M
C) 4.3 ×\times 10-4 M
D) 6.7 ×\times 10-5 M
E) None of these choices is correct.

F) A) and D)
G) A) and C)

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