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How many stereogenic centers are present in the following compound? How many stereogenic centers are present in the following compound?   A)  0 B)  1 C)  2 D)  3


A) 0
B) 1
C) 2
D) 3

E) B) and D)
F) A) and B)

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Which of the following compounds does not have a plane of symmetry? Which of the following compounds does not have a plane of symmetry?   A)  Only I and II B)  Only II C)  Only III and IV D)  Only I, II and IV


A) Only I and II
B) Only II
C) Only III and IV
D) Only I, II and IV

E) B) and D)
F) None of the above

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How many stereogenic centers are present in gabapentin, used clinically to treat seizures and certain types of chronic pain? How many stereogenic centers are present in gabapentin, used clinically to treat seizures and certain types of chronic pain?   A)  0 B)  1 C)  2 D)  3


A) 0
B) 1
C) 2
D) 3

E) A) and D)
F) A) and C)

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What is the relationship between the following compounds? What is the relationship between the following compounds?   A)  Constitutional isomers B)  Diastereomers C)  Enantiomers D)  Identical


A) Constitutional isomers
B) Diastereomers
C) Enantiomers
D) Identical

E) A) and B)
F) B) and C)

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Rank the following groups in order of decreasing priority according to the Cahn-Ingold-Prelog system. COOHHNH2OH I  II  III  IV \begin{array} { c c c c } - \mathrm { COOH } & - \mathrm { H } & - \mathrm { NH } _ { 2 } & - \mathrm { OH } \\\text { I } & \text { II } & \text { III } & \text { IV }\end{array}


A) I > III > IV > II
B) III > IV > I > II
C) IV > III > I > II
D) IV > I > III > II

E) All of the above
F) C) and D)

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What is the relationship between the following compounds? What is the relationship between the following compounds?   A)  Constitutional isomers B)  Diastereomers C)  Enantiomers D)  Identical


A) Constitutional isomers
B) Diastereomers
C) Enantiomers
D) Identical

E) A) and B)
F) A) and C)

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A natural product was isolated in the laboratory, and its observed rotation was +10° when measured in a 1 dm sample tube containing 1.0 g of compound in 10 mL of H2O. What is the specific rotation of this compound?


A) -10°
B) +100°
C) +10°
D) -100°

E) C) and D)
F) None of the above

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How many stereogenic centers are present in fructose, a simple sugar? How many stereogenic centers are present in fructose, a simple sugar?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) B) and C)
F) None of the above

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How many stereogenic centers are present in the following molecule? How many stereogenic centers are present in the following molecule?   A)  1 B)  2 C)  4 D)  5


A) 1
B) 2
C) 4
D) 5

E) All of the above
F) None of the above

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Rank the following groups in order of decreasing priority according to the Cahn-Ingold-Prelog system. CH2CH3CH3HCH(CH3) 2 I  II  III  IV \begin{array} { c c c c } - \mathrm { CH } _ { 2 } \mathrm { CH } _ { 3 } & - \mathrm { CH } _ { 3 } & - \mathrm { H } & - \mathrm { CH } \left( \mathrm { CH } _ { 3 } \right) _ { 2 } \\\text { I } & \text { II } & \text { III } & \text { IV }\end{array}


A) I > II > IV > III
B) IV > II > I > III
C) IV > I > II > III
D) III > II > I> IV

E) A) and B)
F) A) and C)

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Which of the following structures has the S configuration? Which of the following structures has the S configuration?   A)  Only I B)  Only II C)  Only I and II D)  I, II and III


A) Only I
B) Only II
C) Only I and II
D) I, II and III

E) A) and D)
F) All of the above

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Which of the following molecules has a plane of symmetry? \begin{array}{l}\begin{array} { l l l l } \text {\mathrm { CHBrClF }}&\text {\(\mathrm { CH } _ { 2 } \mathrm { BrCl }\) }&\text {\(\mathrm { CH } _ { 3 } \mathrm { CHClBr }\) }&\text {\(\mathrm { CH } _ { 3 } \mathrm { CH } _ { 2 } \mathrm { CHBrF }\) }\\I&II&III&IV\end{array}\end{array}


A) I
B) II
C) III
D) IV

E) A) and D)
F) A) and C)

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Which of the following structures has the R configuration? Which of the following structures has the R configuration?   A)  Only I B)  Only II C)  Only I and II D)  I, II and III


A) Only I
B) Only II
C) Only I and II
D) I, II and III

E) A) and B)
F) B) and C)

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Which of the following structures has the R configuration? Which of the following structures has the R configuration?   A)  Only I B)  Only II C)  Only I and II D)  I, II and III


A) Only I
B) Only II
C) Only I and II
D) I, II and III

E) A) and B)
F) C) and D)

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Rank the following groups in order of decreasing priority according to the Cahn-Ingold-Prelog system. CH=CH2CH3CHOOH I  II  III  IV \begin{array} { c c c c } - \mathrm { CH } = \mathrm { CH } _ { 2 } & - \mathrm { CH } _ { 3 } & - \mathrm { CHO } & - \mathrm { OH } \\\text { I } & \text { II } & \text { III } & \text { IV }\end{array}


A) IV > III > I > II
B) IV > I > III > II
C) III > IV > I > II
D) II > I > III > IV

E) A) and C)
F) B) and C)

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What is the relationship between the following two compounds? What is the relationship between the following two compounds?   A)  Stereoisomers B)  Constitutional isomers C)  Identical D)  Not isomers, different compounds


A) Stereoisomers
B) Constitutional isomers
C) Identical
D) Not isomers, different compounds

E) All of the above
F) A) and B)

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What is the relationship between the following two compounds? What is the relationship between the following two compounds?   A)  Constitutional isomers B)  Identical C)  Stereoisomers D)  Not isomers, different compounds


A) Constitutional isomers
B) Identical
C) Stereoisomers
D) Not isomers, different compounds

E) All of the above
F) A) and B)

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What is the relationship between the following compounds? What is the relationship between the following compounds?   A)  Constitutional isomers B)  Diastereomers C)  Enantiomers D)  Identical


A) Constitutional isomers
B) Diastereomers
C) Enantiomers
D) Identical

E) B) and C)
F) All of the above

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Which of the following compounds are meso? Which of the following compounds are meso?   A)  Only I B)  Only II C)  I and II D)  Neither


A) Only I
B) Only II
C) I and II
D) Neither

E) None of the above
F) B) and D)

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How many isomers (constitutional and stereoisomers) exist for dimethylcyclobutane?


A) 3
B) 4
C) 5
D) 6

E) A) and B)
F) A) and C)

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