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Which orbital has the highest energy in the rubidium atom?


A) 4p
B) 4s
C) 5s
D) 1s
E) 4d

F) A) and D)
G) A) and E)

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The energy equation for a particle in a cubic box of dimensions Lx = Ly = Lz is Enx, ny, nz = The energy equation for a particle in a cubic box of dimensions Lx = L<sub>y</sub> = Lz is E<sub>nx, ny, nz</sub> =    Assume that 8 electrons occupy the allowed energy levels and that 2 electrons can occupy each allowed energy level.  Assume that 8 electrons occupy the allowed energy levels and that 2 electrons can occupy each allowed energy level. The energy equation for a particle in a cubic box of dimensions Lx = L<sub>y</sub> = Lz is E<sub>nx, ny, nz</sub> =    Assume that 8 electrons occupy the allowed energy levels and that 2 electrons can occupy each allowed energy level.

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A. 2
B. 6
...

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In which groups do all the elements have the same number of valence electrons?


A) O, S, Se
B) N, As, Se
C) Ag, Cd, Ar
D) Na, Ca, Ba
E) N, O, Br

F) C) and D)
G) A) and B)

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Consider the following portion of the energy-level diagram for hydrogen: Consider the following portion of the energy-level diagram for hydrogen:   -What is the probability of finding a particle in a one-dimensional box in energy level n = 4 between x = L/4 and x = L/2? (L is the length of the box.)  A)  50% B)  12.5% C)  33% D)  25% E)  37.5% -What is the probability of finding a particle in a one-dimensional box in energy level n = 4 between x = L/4 and x = L/2? (L is the length of the box.)


A) 50%
B) 12.5%
C) 33%
D) 25%
E) 37.5%

F) A) and E)
G) C) and D)

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How many unpaired electrons does chlorine have in its ground state?


A) 2
B) 3
C) 17
D) 1
E) none of these

F) B) and D)
G) A) and B)

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What is the electron configuration for the chromium atom?


A) [Kr] 4s13d5
B) [Ar] 4s23d4
C) [Kr] 4s23d4
D) [Ar] 4s13d5
E) none of these

F) A) and D)
G) None of the above

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What is the wavelength, in nanometers, of a photon of light whose frequency is 5.40 × 1014 Hz?


A) 1.19 × 10-7 nm
B) 2.72 × 102 nm
C) 5.56 × 102 nm
D) 1.80 × 102 nm
E) 3.68 × 102 nm

F) A) and C)
G) A) and B)

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An electron in a one-dimensional box requires energy with wavelength 8080 nm to excite it from the n = 2 energy level to the n = 3 energy level. Calculate the length of the box.


A) 1.50 nm
B) 3.00 nm
C) 1.00 nm
D) 2.50 nm
E) 3.50 nm

F) B) and E)
G) A) and E)

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Given the electron configurations of the following neutral atoms, identify the element, and state the number of unpaired electrons in its ground state. -[Ar] 4s23d7

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The element is Co wi...

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Place the elements C, N, and O in order of increasing ionization energy.


A) N, O, C
B) C, N, O
C) O, N, C
D) C, O, N
E) none of these

F) B) and D)
G) B) and C)

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What is the electron configuration of Co3+?


A) [Ar] 3d6
B) [Ar] 4s24d4
C) [Ar] 3d4
D) [Ar] 4s23d4
E) none of these

F) B) and E)
G) A) and B)

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Given the electron configurations of the following neutral atoms, identify the element, and state the number of unpaired electrons in its ground state. -[Xe] 4f146s25d2

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The element is Hf wi...

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The energy equation for a particle in a cubic box of dimensions Lx = Ly = Lz is Enx, ny, nz = The energy equation for a particle in a cubic box of dimensions Lx = L<sub>y</sub> = Lz is Enx<sub>,</sub> <sub>ny, nz</sub> =   For a particle in a cubic box, how many degenerate energy levels have energy equal to 14 h<sup>2</sup>/8 mL<sup>2</sup>? A)  1 B)  12 C)  6 D)  8 E)  3 For a particle in a cubic box, how many degenerate energy levels have energy equal to 14 h2/8 mL2?


A) 1
B) 12
C) 6
D) 8
E) 3

F) D) and E)
G) A) and B)

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Write the electron configuration for the following: -Cu

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1s22s22p63s23p...

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Which of the following statements is(are) true? i. An excited atom can return to its ground state by absorbing electromagnetic radiation.II. The energy of an atom is increased when electromagnetic radiation is emitted from it.III. The energy of electromagnetic radiation increases as its frequency increases.IV. An electron in the n = 4 state in the hydrogen atom can go to the n = 2 state by emitting electromagnetic radiation at the appropriate frequency.V. The frequency and wavelength of electromagnetic radiation are inversely proportional to each other.


A) III, V
B) II, III, IV
C) I, II, IV
D) I, II, III
E) III, IV, V

F) C) and D)
G) A) and D)

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In an investigation of the electronic absorption spectrum of a particular element, it is found that a photon having λ = 500 nm provides just enough energy to promote an electron from the second quantum level to the third. From this information, we can deduce


A) the energy of the n = 2 level.
B) the sum of the energies of the n = 2 and n = 3 levels.
C) the difference between the energies of the n = 2 and n = 3 levels.
D) the energy of the n = 3 level.
E) all of these.

F) A) and B)
G) A) and E)

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From the following list of observations, choose the one that most clearly supports the conclusion that the mass of the atom is located mainly in the nucleus.


A) the emission spectrum of hydrogen
B) the photoelectric effect
C) diffraction
D) the scattering of alpha particles by metal foil
E) cathode "rays"

F) B) and E)
G) A) and B)

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Light has a wavelength of 5.6 × 102 nm. What is the energy of a photon of this light?


A) 2.53× 1018 J
B) 3.95 × 10-20 J
C) 1.24 × 10-18 J
D) 1.18 × 10-19 J
E) 3.55 × 10-19 J

F) All of the above
G) B) and C)

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How many electrons can be described by the quantum numbers n = 4, l = 3, ml = 0?


A) 2
B) 10
C) 6
D) 0
E) 14

F) D) and E)
G) All of the above

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Consider the following orderings. I. Al < Si < P < Cl II. Be < Mg < Ca < Sr III. I < Br < Cl < F IV. Na+ < Mg2+ < Al3+ < Si4+ -Which of the following statements is true of second ionization energies?


A) That of Al is higher than that of Mg because Mg wants to lose the second electron, so it is easier to take the second electron away.
B) That of Al is lower than that of Mg because the second electron taken from Al is in a p orbital, so it is easier to take away.
C) That of Al is lower than that of Mg because Mg wants to lose the second electron, so the energy change is greater.
D) The second ionization energies are equal for Al and Mg.
E) That of Al is higher than that of Mg because the electrons are taken from the same energy level, but the Al atom has one more proton.

F) B) and C)
G) D) and E)

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