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The endpoint is used to estimate the equivalence point.

A) True
B) False

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When a strong acid is titrated with a weak base,the pH at the equivalence point


A) is greater than 7.0.
B) is equal to 7.0.
C) is less than 7.0.
D) is equal to the pKa of the conjugate acid.
E) is equal to the pKb of the base.

F) None of the above
G) B) and C)

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Describe how to make a sodium formate (HCOONa)/formic acid (HCOOH)buffer that has a pH of 4.77.Ka = 1.7 × 10-4

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Prepare a solution h...

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What is the pH of a solution that consists of 0.50 M H2C6H6O6 (ascorbic acid) and 0.75 M NaHC6H6O6 (sodium ascorbate) ? [Ka (H2C6H6O6) = 6.8 × 10-5]


A) 3.76
B) 3.99
C) 4.34
D) 4.57
E) 5.66

F) C) and D)
G) A) and C)

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What happens to the solution if sodium acetate is added to a solution of acetic acid? CH3COOH(aq) What happens to the solution if sodium acetate is added to a solution of acetic acid? CH<sub>3</sub>COOH(aq)    H<sup>+</sup> (aq) + CH<sub>3</sub>COO<sup>-</sup> (aq)  A) The equilibrium shifts to the right. B) There is an increase in percent ionization of acetic acid. C) Less of hydrogen ion is consumed. D) There is an increased concentration of acetate ions. E) Less of the acetate ion is consumed. H+ (aq) + CH3COO- (aq)


A) The equilibrium shifts to the right.
B) There is an increase in percent ionization of acetic acid.
C) Less of hydrogen ion is consumed.
D) There is an increased concentration of acetate ions.
E) Less of the acetate ion is consumed.

F) C) and D)
G) A) and D)

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The molar solubility of magnesium carbonate is 1.8 × 10-4 mol/L.What is Ksp for this compound?


A) 1.8 × 10-4
B) 3.6 × 10-4
C) 1.3 × 10-7
D) 3.2 × 10-8
E) 2.8 × 10-14

F) A) and C)
G) None of the above

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Which compound has the lowest solubility in pure water?


A) Ag2C2O4,Ksp = 1.0 × 10-11
B) PbCl2,Ksp = 1.7 × 10-5
C) FePO4,Ksp = 1.3 × 10-22
D) Ca3(PO4) 2,Ksp = 1.2 × 10-26
E) MgF2,Ksp = 6.9 × 10-9

F) A) and D)
G) B) and C)

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Explain the effect on the ionization of the acetic acid when sodium acetate is added to a solution of acetic acid? CH3COOH(aq) Explain the effect on the ionization of the acetic acid when sodium acetate is added to a solution of acetic acid? CH<sub>3</sub>COOH(aq)

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H+(aq)+ CH3COO-(aq)The equilibriu...

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The pH of a solution that is 0.20 M CH3COOH and 0.20 M CH3COONa should be higher than the pH of a 0.20 M CH3COOH solution.

A) True
B) False

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A 35.0-mL sample of 0.20 M LiOH is titrated with 0.25 M HCl.What is the pH of the solution after 23.0 mL of HCl have been added to the base?


A) 1.26
B) 1.67
C) 12.33
D) 12.74
E) 13.03

F) A) and E)
G) C) and D)

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Explain why it is important that the amount of added strong acid not exceed the original amount of conjugate base present in the buffer.

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All the added strong acid must...

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What is the pH of a solution that is 0.410 M in HOCl and 0.050 M in NaOCl? [Ka(HOCl) = 3.2 × 10-8]


A) 0.39
B) 3.94
C) 6.58
D) 7.49
E) 8.40

F) A) and B)
G) A) and C)

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When a weak acid is titrated with a strong base,the pH at the equivalence point


A) is greater than 7.0.
B) is equal to 7.0.
C) is less than 7.0.
D) is equal to the pKa of the acid.
E) is equal to the pKb of the conjugate base.

F) A) and B)
G) B) and E)

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Will a precipitate (ppt) form when 20.0 mL of 1.1 × 10-3 M Ba(NO3) 2 are added to 80.0 mL of 8.4 ×10-4M Na2CO3?


A) Yes,the ppt is Ba(NO3) 2.
B) Yes,the ppt is NaNO3.
C) Yes,the ppt is BaCO3.
D) Yes,the ppt is Na2CO3.
E) No,a precipitate will not form.

F) C) and D)
G) A) and E)

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Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution once 25.0 mL of titrant have been added? (Solvent water molecules are omitted for clarity.)


A) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution once 25.0 mL of titrant have been added? (Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
B) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution once 25.0 mL of titrant have been added? (Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
C) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution once 25.0 mL of titrant have been added? (Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
D) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution once 25.0 mL of titrant have been added? (Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
E) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution once 25.0 mL of titrant have been added? (Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)

F) B) and E)
G) None of the above

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A ___________ helps maintain a constant pH even after the addition of acid or base.

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A buffer is prepared by adding 1.00 L of 1.0 M HCl to 750 mL of 1.5 M NaHCOO.What is the pH of this buffer? [Ka (HCOOH) = 1.7 × 10-4]


A) 2.87
B) 3.72
C) 3.82
D) 3.95
E) 4.66

F) B) and E)
G) None of the above

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The solubility of magnesium phosphate is 2.27 × 10-3 g/1.0 L of solution.What is the Ksp for Mg3(P O4) 2?


A) 7.46 × 10-11
B) 2.68 × 10-9
C) 5.19 × 10-24
D) 4.80 × 10-26
E) 1.20 × 10-26

F) A) and B)
G) A) and C)

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A(n)________________ is a measure of the tendency of a metal ion to form a particular complex ion and is the equilibrium constant for the complex ion formation.

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formation constant o...

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What is the ion product expression for magnesium fluoride,MgF2?


A) What is the ion product expression for magnesium fluoride,MgF<sub>2</sub>? A)    B)    C)    D)    E)
B) What is the ion product expression for magnesium fluoride,MgF<sub>2</sub>? A)    B)    C)    D)    E)
C) What is the ion product expression for magnesium fluoride,MgF<sub>2</sub>? A)    B)    C)    D)    E)
D) What is the ion product expression for magnesium fluoride,MgF<sub>2</sub>? A)    B)    C)    D)    E)
E) What is the ion product expression for magnesium fluoride,MgF<sub>2</sub>? A)    B)    C)    D)    E)

F) A) and E)
G) A) and B)

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