Question 1

For the reaction BrO3- + 5Br- + 6H+ → 3Br2 + 3H2O at a particular time,-Δ[BrO3-]/Δt = 1.5 × 10-2 M/s.What is -Δ[Br-]/Δt at the same instant?

Accepted Answer

A)  13 M/s
B)  7.5 × 10-2 M/s
C)  1.5 × 10-2 M/s
D)  3.0 × 10-3 M/s
E)  330 M/sF) A) and D)
G) B) and D) B

Question 2

The _______________ is the equation relating the rate of the reaction to the concentration of molecule.

Accepted Answer

The answer of The _______________ is the equation relating the...

Question 3

The ____________________ is the name given to the sequence of steps that sum to give the overall reaction.

Accepted Answer

The answer of The ____________________ is the name given to...

Question 4

Ammonium cyanate (NH4CNO) reacts to form urea (N H2CON H2) .At 65°C the rate constant,k,is 3.60 L • mol-1 • s-1.What is the rate law for this reaction?

Accepted Answer

A)  Rate = (3.60 L • mol-1 • s-1) [NH4CNO]
B)  Rate = (3.60 L • mol-1 • s-1) [NH4CNO]2
C)  Rate = (0.28 mol • L-1 • s-1) [NH4CNO]
D)  Rate = (0.28 mol • L-1 • s-1) [NH4CNO]2
E)  Rate = (3.60 L • mol-1 • s-1) [N H2CON H2]-1F) B) and C)
G) A) and E) B

Question 5

Which is the correct unit for a first-order rate constant?

Accepted Answer

A)  s-1
B)  M • s-1
C)  M • s
D)  M -1 • s-1
E)  M -2 • s-1F) C) and D)
G) B) and E)

Question 6

The rate law for the reaction 3A → C is rate = 4.36 × 10-2 L• mol-1 • h-1[A]2 What is the half-life for the reaction if the initial concentration of A is 0.250 M?

Accepted Answer

A)  0.0109 h
B)  0.0629 h
C)  15.9 h
D)  23.9 h
E)  91.7 hF) A) and B)
G) B) and C)

Question 7

What statement below best describes the graph representing the integrated first-order rate law?

Accepted Answer

A)  A plot of [A]t vs.t yields a straight line with a negative slope equal to -k.
B)  A plot of 1/[A]t vs.t yields a straight line with a negative slope equal to k.
C)  A plot of ln[A]t vs.t yields a straight line with a positive slope equal to -k.
D)  A plot of ln[A]t vs.t yields a straight line with a negative slope equal to -k.
E)  A plot of 1/[A]t vs.t yields a straight line with a positive slope equal to k.F) B) and C)
G) B) and D)

Question 8

When the reaction A → B + C is studied,a plot 1/[A]t vs.time gives a straight line with a positive slope.What is the order of the reaction with respect to A?

Accepted Answer

A)  Zero
B)  First
C)  Second
D)  Third
E)  More information is needed to determine the order.F) A) and C)
G) A) and E)

Question 9

The units of the rate of reaction depend on the order of the reaction.

Accepted Answer

A) True 
 B)False

Question 10

A ________-__________________ is a reaction whose rate depends on the concentration of one of the reactants squared.

Accepted Answer

second-ord...

Question 11

What is the integrated rate law for a zeroth-order reaction?

Accepted Answer

A)  rate = k[A]t
B)   
C)   
D)   
E)   F) A) and D)
G) C) and D)

Question 12

For a zeroth-order reaction,if the concentration of reactant A is plotted vs.time,which corresponds to the slope of this plot?

Accepted Answer

A)  1/[A]
B)  k
C)  1/k
D)  ln[A]
E)  -kF) A) and D)
G) A) and B)

Question 13

The isomerization of methyl isocyanide,CH3NC → CH3CN,follows first-order kinetics.The half-lives were found to be 161 min at 199°C and 12.5 min at 230.°C.Calculate the activation energy for this reaction.(R = 8.314 J/mol • K)

Accepted Answer

A)  6.17 × 10-3 kJ/mol
B)  31.4 kJ/mol
C)  78.2 kJ/mol
D)  124 kJ/mol
E)  163 kJ/molF) C) and D)
G) B) and E)

Question 14

Consider the following reaction 8A(g) + 5B(g) → 8C(g) + 6D(g) 
If [C] is increasing at the rate of 4.0 mol L-1 • s-1,at what rate is [B] changing?

Accepted Answer

A)  -0.40 mol L-1• s-1
B)  -2.5 mol L-1• s-1
C)  -4.0 mol L-1• s-1
D)  -5.0 mol L-1• s-1
E)  -6.4 mol L-1• s-1F) B) and C)
G) B) and D)

Question 15

For the reaction X + Y → Z,the reaction rate is found to depend only upon the concentration of X.A plot of 1/X versus time gives a straight line. 2 C) rate = k [X][Y] D) rate = k [X]2[Y] E) rate = k [X]2/[Y]" class="answers-bank-image d-inline" rel="preload" > What is the rate law for this reaction?

Accepted Answer

A)  rate = k [X]
B)  rate = k [X]2
C)  rate = k [X][Y]
D)  rate = k [X]2[Y]
E)  rate = k [X]2/[Y]F) A) and E)
G) All of the above B

Question 16

The reaction A + 2B → products was found to follow the rate law: rate = k[A]2[B].Predict by what factor the rate of reaction will increase when the concentration of A is doubled,the concentration of B is tripled,and the temperature remains constant.

Accepted Answer

A)  5
B)  6
C)  12
D)  18
E)  None of theseF) A) and B)
G) All of the above

Question 17

What is the name given for the study of how fast reactions take place?

Accepted Answer

A)  Reaction rate
B)  Activation energy
C)  Chemical kinetics
D)  Reactivity
E)  Half-lifeF) A) and E)
G) B) and E)

Question 18

What is the half-life for a first-order reaction?

Accepted Answer

A)  t1/2 = k
B)  t1/2 = 1/k[A]o
C)  t1/2 = 0.693/k[A]o
D)  t1/2 = [A]o/2k
E)  t1/2 = 0.693/kF) A) and C)
G) C) and D)

Question 19

Tetrafluoroethylene,C2F4,can be converted to octafluorocyclobutane,which can be used as a refrigerant or an aerosol propellant.A plot of 1/[C2F4] vs.time gives a straight line with a slope of 0.0448 L •mol-1 • s-1.What is the rate law for this reaction?

Accepted Answer

A)  Rate = 0.0448 (L • mol-1 • s-1) [C2F4]
B)  Rate = 22.3 (mol • L-1 • s) [C2F4]
C)  Rate = 0.0448 (L • mol-1 • s-1) [C2F4]2
D)  Rate = 22.3 (mol • L-1 • s) [C2F4]2
E)  Rate = 0.0448 s-1 [C2F4]F) B) and E)
G) None of the above

Question 20

The following diagram represents the first-order decomposition of A to form X according to the following balanced chemical equation: A → X.Each sphere represents 1.0 mmol of atoms,and the volume of the box is 1.0 L. -1 B) 0.046 s-1 C) 0.067 s-1 D) 15 s-1 E) 17 s-1" class="answers-bank-image d-inline" rel="preload" > What is the rate constant?

Accepted Answer

A)  0.019 s-1
B)  0.046 s-1
C)  0.067 s-1
D)  15 s-1
E)  17 s-1F) B) and E)
G) C) and D)

Exam 14: Chemical Kinetics

For the reaction BrO3- + 5Br- + 6H+ → 3Br2 + 3H2O at a particular time,-Δ[BrO3-]/Δt = 1.5 × 10-2 M/s.What is -Δ[Br-]/Δt at the same instant?

Correct AnswerverifiedB

The _______________ is the equation relating the rate of the reaction to the concentration of molecule.

Correct AnswerverifiedShow Answer

The ____________________ is the name given to the sequence of steps that sum to give the overall reaction.

Correct AnswerverifiedShow Answer

Ammonium cyanate (NH4CNO) reacts to form urea (N H2CON H2) .At 65°C the rate constant,k,is 3.60 L • mol-1 • s-1.What is the rate law for this reaction?

Correct AnswerverifiedB

Which is the correct unit for a first-order rate constant?

Correct AnswerverifiedShow Answer

The rate law for the reaction 3A → C is rate = 4.36 × 10-2 L• mol-1 • h-1[A]2 What is the half-life for the reaction if the initial concentration of A is 0.250 M?

Correct AnswerverifiedShow Answer

What statement below best describes the graph representing the integrated first-order rate law?

Correct AnswerverifiedShow Answer

When the reaction A → B + C is studied,a plot 1/[A]t vs.time gives a straight line with a positive slope.What is the order of the reaction with respect to A?

Correct AnswerverifiedShow Answer

The units of the rate of reaction depend on the order of the reaction.

Correct AnswerverifiedShow Answer

A ________-__________________ is a reaction whose rate depends on the concentration of one of the reactants squared.

Correct Answerverifiedsecond-ord...View AnswerShow Answer

What is the integrated rate law for a zeroth-order reaction?

Correct AnswerverifiedShow Answer

For a zeroth-order reaction,if the concentration of reactant A is plotted vs.time,which corresponds to the slope of this plot?

Correct AnswerverifiedShow Answer

The isomerization of methyl isocyanide,CH3NC → CH3CN,follows first-order kinetics.The half-lives were found to be 161 min at 199°C and 12.5 min at 230.°C.Calculate the activation energy for this reaction.(R = 8.314 J/mol • K)

Correct AnswerverifiedShow Answer

Consider the following reaction 8A(g) + 5B(g) → 8C(g) + 6D(g) If [C] is increasing at the rate of 4.0 mol L-1 • s-1,at what rate is [B] changing?

Correct AnswerverifiedShow Answer

For the reaction X + Y → Z,the reaction rate is found to depend only upon the concentration of X.A plot of 1/X versus time gives a straight line. What is the rate law for this reaction?

Correct AnswerverifiedB

The reaction A + 2B → products was found to follow the rate law: rate = k[A]2[B].Predict by what factor the rate of reaction will increase when the concentration of A is doubled,the concentration of B is tripled,and the temperature remains constant.

Correct AnswerverifiedShow Answer

What is the name given for the study of how fast reactions take place?

Correct AnswerverifiedShow Answer

What is the half-life for a first-order reaction?

Correct AnswerverifiedShow Answer

Tetrafluoroethylene,C2F4,can be converted to octafluorocyclobutane,which can be used as a refrigerant or an aerosol propellant.A plot of 1/[C2F4] vs.time gives a straight line with a slope of 0.0448 L •mol-1 • s-1.What is the rate law for this reaction?

Correct AnswerverifiedShow Answer

The following diagram represents the first-order decomposition of A to form X according to the following balanced chemical equation: A → X.Each sphere represents 1.0 mmol of atoms,and the volume of the box is 1.0 L. What is the rate constant?

Correct AnswerverifiedShow Answer

For the reaction BrO₃^- + 5Br^- + 6H⁺ → 3Br² + 3H₂O at a particular time,-Δ[BrO₃^-]/Δt = 1.5 × 10^-2 M/s.What is -Δ[Br^-]/Δt at the same instant?

Correct Answer
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B

Correct Answer
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Correct Answer
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Ammonium cyanate (NH₄CNO) reacts to form urea (N H₂CON H₂) .At 65°C the rate constant,k,is 3.60 L • mol^-1 • s^-1.What is the rate law for this reaction?

Correct Answer
verified
B

Correct Answer
verified

The rate law for the reaction 3A → C is rate = 4.36 × 10^-2 L• mol^-1 • h^-1[A]² What is the half-life for the reaction if the initial concentration of A is 0.250 M?

Correct Answer
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Correct Answer
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Correct Answer
verified

Correct Answer
verified

A -__________ is a reaction whose rate depends on the concentration of one of the reactants squared.

Correct Answer
verified
second-ord...
View Answer

Correct Answer
verified

Correct Answer
verified

The isomerization of methyl isocyanide,CH₃NC → CH₃CN,follows first-order kinetics.The half-lives were found to be 161 min at 199°C and 12.5 min at 230.°C.Calculate the activation energy for this reaction.(R = 8.314 J/mol • K)

Correct Answer
verified

Consider the following reaction 8A(g) + 5B(g) → 8C(g) + 6D(g) If [C] is increasing at the rate of 4.0 mol L^-1 • s^-1,at what rate is [B] changing?

Correct Answer
verified

Correct Answer
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B

The reaction A + 2B → products was found to follow the rate law: rate = k[A]²[B].Predict by what factor the rate of reaction will increase when the concentration of A is doubled,the concentration of B is tripled,and the temperature remains constant.

Correct Answer
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Correct Answer
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Correct Answer
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Tetrafluoroethylene,C₂F₄,can be converted to octafluorocyclobutane,which can be used as a refrigerant or an aerosol propellant.A plot of 1/[C₂F₄] vs.time gives a straight line with a slope of 0.0448 L •mol^-1 • s^-1.What is the rate law for this reaction?

Correct Answer
verified

Correct Answer
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